CHINESE JOURNAL OF ENERGETIC MATERIALS
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丁羟四组元推进剂的宽温围压单向拉伸力学行为
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1.航天化学动力技术重点实验室, 湖北 襄阳 441003;2.湖北航天化学技术研究所, 湖北 襄阳 441003

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国家自然科学基金资助(22105067)


Uniaxial Tensile Properties of Butadiol Quaternary Propellant under Confining Pressure and Wide Temperature
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1.Science and Technology on Aerospace Chemical Power Laboratory, Xiangyang 441003, China;2.Hubei Institute of Aerospace Chemotechnology, Xiangyang 441003, China

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    摘要:

    为了研究丁羟四组元推进剂在宽温围压条件下的单向拉伸力学性能,采用宽温-围压气体试验系统研究了不同温度(-50 ℃、20 ℃和70 ℃)、不同围压(0.1 MPa、2 MPa与8 MPa)与不同拉伸速率(100 mm·min-1、1000 mm·min-1和4200 mm·min-1)下推进剂力学性能的变化规律。采用SEM扫描电镜与微米CT相结合的手段从细观层面分析宏观力学性能发展的内在细观原因,以此揭示外载荷对高固含量推进剂力学性能的影响机制。研究表明,常温与高温条件下,推进剂的损伤以“脱湿”为主;低温常压下则主要为“脱湿”和颗粒的韧断,当围压增大时会向颗粒的脆断转变,但延伸率随围压的增大仍然增大,分析认为主要是围压抑制了孔洞的产生和损伤的演化;在高围压不同拉伸速率下,常温和高温下推进剂表现出来的力学性能较为接近,这是因为高温会使粘合剂基体与固体填料之间的相互作用减弱,推进剂出现更严重的脱湿,而高围压则会抑制“脱湿”而减弱温度的影响;采用时压等效叠加原理(TPSP)进行最大抗拉强度主曲线拟合分析时,在低温-50 ℃条件下,时间-压强压位移因子与对应围压之间的关系并不符合标准形式,对于高固含量的推进剂而言TPSP叠加原理具有一定的使用局限性。

    Abstract:

    In order to study the uniaxial tensile mechanical properties of hydroxyl tetrade propellant under wide temperature and confining pressure, the mechanical properties of propellants under different temperatures(-50 ℃, 20 ℃ and 70 ℃), confining pressures(0.1, 2 MPa and 8 MPa) and tensile rates(100, 1000 mm·min-1 and 4200 mm·min-1) experiments were conducted by using a wide-temperature-confining pressure gas test system. The internal microscopic reasons for the development of macroscopic mechanical properties were analyzed by means of scanning electron microscopy (SEM) and micron CT, with the main of revealing the influence mechanism of external load on mechanical properties of high solid content propellants. The results show that the damage of propellant is mainly attribute to“de-wetting” at room temperature and high temperature. At low temperature and atmospheric pressure, the particles suffer the "de-wetting" and ductile fracture. When the confining pressure increasing, it would change to brittle fracture of particles. Nevertheless, the elongation still increases with the increase of confining pressure. Under high confining pressure and different tensile rates, the mechanical properties of the propellant at room temperature and high temperature are similar. Because at this conditions, high temperature weakens the interaction between binder matrix and solid filler, and the “de-wetting” of the propellant are more seriously, but high confining pressure inhibits the “de-wetting” and weakens the influence of temperature. When the time-pressure equivalent superposition principle (TPSP) is used to carry out the fitting analysis of the principal curve of the maximum tensile strength, at low of -50 ℃, the relationship between the time-pressure displacement factor and the corresponding confining pressure does not conform to the standard form, and the superposition principle of TPSP has certain limitations for the use of high solid content propellants.

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引用本文

李春涛,李伟,庞爱民,等.丁羟四组元推进剂的宽温围压单向拉伸力学行为[J].含能材料, 2022, 30(8):793-803. DOI:10.11943/CJEM2022032.
LI Chun-tao, LI Wei, PANG Ai-min, et al. Uniaxial Tensile Properties of Butadiol Quaternary Propellant under Confining Pressure and Wide Temperature[J]. Chinese Journal of Energetic Materials, 2022, 30(8):793-803. DOI:10.11943/CJEM2022032.

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  • 收稿日期: 2022-02-18
  • 最后修改日期: 2022-07-14
  • 录用日期: 2022-07-11
  • 在线发布日期: 2022-07-12
  • 出版日期: 2022-08-25