CHINESE JOURNAL OF ENERGETIC MATERIALS
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高氯酸铵的热分解
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刘子如(1940-),研究员,博导,从事火炸药热化学、热分解动力学的热分析研究。

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The Thermal Decomposition of Ammonium Perchlorate
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    摘要:

    用差热分析及其与FTIR联用技术研究了两种粒度高氯酸铵(AP)的热分解过程,提出了AP晶体分解的“局部化学”现象,通过FTIR实时跟踪检测气体产物,并结合文献报道,提出了AP两个阶段分解的不同机理。

    Abstract:

    The thermal decompositions of two kinds of NH4ClO4 (AP) with different grain size were investigated by DTA and TC-FTIR coupling. It is proposed that the decomposition of AP crystal obeys the process of “topochemistry ” and it is explained that there are two steps in the decomposition of the coarse grain size. On the basis of the gaseous products identified by real-time and rapid-scan FTIR and reported results in the literatures, the different mechanisms of the two steps during AP decomposition process are suggested.

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刘子如,阴翠梅,孔扬辉,等.高氯酸铵的热分解[J].含能材料,2000,8(2):75-79.
LIU Zi-ru, YIN Cui-mei, KONG Yang-hui, et al. The Thermal Decomposition of Ammonium Perchlorate[J]. Chinese Journal of Energetic Materials, 2000, 8(2):75-79.

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  • 收稿日期: 2000-01-31
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  • 在线发布日期: 2011-11-02
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