CHINESE JOURNAL OF ENERGETIC MATERIALS
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NH4NO3和NH4ClO4的绝热分解研究
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钱新明(1967-),男,副教授,博士,主要从事有关安全方面的研究。

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国家自然科学基金资助项目(编号:19802004)


Study on the Thermal Decomposition of Ammonium Nitrate and Ammonium Perchlorate by Accelerating Rate Calorimeter
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    摘要:

    用加速热量仪研究了硝酸铵和高氯酸铵的热分解过程,得到了它们的绝热分解温度和压力随时间的变化曲线,并分别计算了这两种物质的动力学参数表观活化能和指前因子。

    Abstract:

    The thermal decompositions of ammonium nitrate(AN) and ammonium perchlorate(AP) are investigated by ARC (Accelerating Rate Calorimeter). The curves of thermal decomposition temperature and pressure versus time for the two systems are obtained. There are obvious differences in decomposition characteristic between the two chemicals. The kinetic parameters such as apparent activation energy and pre-exponential factor of the thermal decomposition of AN and AP are calculated respectively.

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钱新明,傅智敏,张文明,等. NH4NO3和NH4ClO4的绝热分解研究[J].含能材料,2001,9(4):156-160.
QIAN Xin-ming, FU Zhi-min, ZHANG Wen-ming, et al. Study on the Thermal Decomposition of Ammonium Nitrate and Ammonium Perchlorate by Accelerating Rate Calorimeter[J]. Chinese Journal of Energetic Materials, 2001, 9(4):156-160.

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  • 收稿日期: 2001-05-21
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  • 在线发布日期: 2011-11-03
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