CHINESE JOURNAL OF ENERGETIC MATERIALS
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国外四嗪四唑类高氮含能材料研究进展
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阳世清(1962-),男,副研究员,博士,从事含能材料、烟火技术与爆破工程等研究工作。

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国家自然科学基金委员会—中国工程物理研究院 “NSAF”联合基金资助(10376042)


Progress in High-nitrogen Energetic Materials Derived from Tetrazine and Tetrazole
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    摘要:

    对国外正在研究的四嗪、四唑类高氮含能材料进行了综述,介绍了部分四嗪、四唑类高氮化合物及其衍生物的合成、理化性质和应用前景,对国外研究的3,6-二肼基-1,2,4,5-四嗪(DHT)、3,3′-偶氮(6-氨基-1,2,4,5-四嗪)(DAAT)、3,6-双(1氢-1,2,3,4-四唑-5-氨基)-1,2,4,5-四嗪(BTATz)、联四唑(BHT)等进行了重点描述。

    Abstract:

    The research developments of high-nitrogen energetic materials are reviewed. The synthesis and properties of some new compounds derivated from tetrazole and tetrazine,especially 3,6-dihydrazino-1,2,4,5-tetrazine(DHT),3,3′-azobis(6-amino-1,2,4,5-tetrazine)(DAAT),3,6-bis (1H-1,2,3,4-tetrazol-5-yl-amino) -1,2,4,5-tetrazine(BTATz) and 5,5′-bitetrazole(BHT) are discussed. Because of their much more positive heats of formation and higher density,these high-nitrogen compounds are unique in their gas generating ability with a little or without smoke and produced residue. They may have a great future for applications in insensitive explosives,low signature propellants,gas generants and low-smoke pyrotechnics.

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阳世清,岳守体.国外四嗪四唑类高氮含能材料研究进展[J].含能材料,2003,11(4):231-235.
YANG Shi-qing, YUE Shou-ti. Progress in High-nitrogen Energetic Materials Derived from Tetrazine and Tetrazole[J]. Chinese Journal of Energetic Materials, 2003, 11(4):231-235.

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  • 收稿日期: 2003-06-30
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  • 在线发布日期: 2011-11-03
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