CHINESE JOURNAL OF ENERGETIC MATERIALS
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钝感双基发射药老化迁移机理及动力学过程
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1.南京理工大学化工学院, 江苏 南京 210094;2.特种能源材料教育部重点实验室(南京理工大学), 江苏 南京 210094

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Aging Migration Mechanism and Kinetic Process of Deterred DB Propellants
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1.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;2.Key Laboratory of Special Energetic Materials (Nanjing University of Science and Technology), Ministry of Education, Nanjing 210094, China

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    摘要:

    为研究钝感双基发射药老化迁移过程及影响因素,利用钝感剂的正态分布特性及Fickian第二扩散定律的推论,建立了钝感发射药老化迁移导致钝感剂浓度分布及燃烧性能变化的理论模型。对6种不同硝化甘油(NG)及邻苯二甲酸二丁酯(DBP)含量的发射药进行不同温度下加速老化实验,采用密闭爆发器测试了不同老化时间后发射药的燃烧性能,分析了发射药老化迁移的动力学过程及热力学影响。理论分析表明,钝感球形发射药燃气生成猛度积分值的增长率随老化时间呈现出较好的线性增长模型。密闭爆发器结果表明,6种发射药加速老化后的动态活度最大值升高百分比随老化时间均呈较强的线性关系,与理论研究结果一致。建立的钝感发射药老化迁移热力学方程与试验结果基本吻合,迁移驱动因子对数与温度的倒数呈现出较为明显的线性负相关。发射药中NG与DBP总含量高于15%时,发射药的迁移驱动因子(动态活度最大值的百分比增长速率)更易受温度影响从而加剧钝感剂迁移导致钝感失效;而NG和DBP的总含量不高于15%时,钝感剂迁移导致失效的速率较为缓慢,更有利于发射药贮存后的使用和射击安全。

    Abstract:

    In order to study the aging migration process and influencing factors of deterred DB propellants, a theoretical model on the deterrent distribution and the change of combustion performance caused by aging migration was established based on the normal distribution characteristics of deterrent and the inference of Fickian second diffusion law. Six kinds of propellants with different contents of nitroglycerin(NG) and dibutyl phthalate(DBP) were treated by accelerated aging experiments at different temperatures and times, and the combustion performances of propellants were tested by closed bomb vessel. The kinetic process and thermodynamic influence of aging migration for propellants were analyzed. Theoretical analysis shows that the integral value growth rate of the dynamic vivacity for deterred spherical propellants presents a good linear growth relationship with aging time. The results of the closed bomb vessel show that the percentage increase of the maximum dynamic activity for the six propellants after accelerated aging also gives a good linear relationship with aging time, which is consistent with the theoretical research results. The established thermodynamic equation of aging migration for deterred propellants is basically consistent with the experimental results, and the logarithm of migration driving factor and the reciprocal of temperature present an obvious linear negative correlation. When the total content of NG and DBP in propellants is greater than 15%, the migration driving factor is more susceptible to the influence of temperature, leading to migration invalidation. When the total content of NG and DBP is less than 15%, the invalidation rate caused by deterrent migration is relatively slow, which is more conducive to the use and shooting safety after the storage of propellants.

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引用本文

梁昊,丁亚军,李世影,等.钝感双基发射药老化迁移机理及动力学过程[J].含能材料, 2021, 29(11):1080-1088. DOI:10.11943/CJEM2021007.
LIANG Hao, DING Ya-jun, LI Shi-ying, et al. Aging Migration Mechanism and Kinetic Process of Deterred DB Propellants[J]. Chinese Journal of Energetic Materials, 2021, 29(11):1080-1088. DOI:10.11943/CJEM2021007.

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历史
  • 收稿日期: 2021-01-06
  • 最后修改日期: 2021-04-24
  • 录用日期: 2021-04-12
  • 在线发布日期: 2021-04-20
  • 出版日期: 2021-11-25