CHINESE JOURNAL OF ENERGETIC MATERIALS
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铝粉含量对GAP钝感推进剂性能的影响
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1.航天化学动力技术重点实验室, 湖北 襄阳 441003;2.湖北航天化学技术研究所, 湖北 襄阳 441003

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空军装备部预研项目(30304)


Influence of Aluminum Powder Contents on Insensitive GAP Propellants
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1.Science and Technology on Aerospace Chemical Power Laboratory, Xiangyang 441003, China;2.Hubei Institute of Aerospace Chemical Technology,Xiangyang 441003, China

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    摘要:

    以铝粉含量为5%、10%、15%和18%的缩水甘油叠氮聚醚(GAP)推进剂配方为研究对象,采用力学拉伸试验机、动态热机械分析仪(DMA)和模拟计算软件等,分析了铝粉含量对推进剂力学性能、界面性能、燃烧性能、安全性能、能量性能和密度等的影响。结果表明,以30 μm铝粉代替320 μm AP,随铝粉含量的提高,推进剂的最大抗拉强度和最大伸长率逐渐增大,界面性能得到进一步改善;推进剂在3~9 MPa下的静态燃速并未发生明显变化但压强指数由0.43降低至0.40。配方中铝粉含量为5%和18%的推进剂危险等级均达1.3级,其中铝粉含量为18%的推进剂配方的撞击和摩擦感度分别为0%和44%,低于铝粉含量为5%的配方(分别为4%和48%);软件模拟计算表明,铝粉加入量的提高使推进剂的能量和密度均呈上升趋势,但推进剂的标准比冲提升趋势趋于平缓。

    Abstract:

    In order to study the influence of aluminum powder on the mechanical property, interface, combustion, safety, energy, density and other performance of propellants, the glycidyl azide polymer (GAP) propellants with 5%, 10%, 15% and 18% aluminum powder were evaluated by tensile testing machine, dynamic thermomechanical analysis (DMA), calculation program and etc. Results show that, with the replacement of 320 μm AP with 30 μm aluminum powder and the increase of aluminum powder contents, the propellant has increasing maximal tensile strength and maximal elongation, and improving interface performance. The burning rates change scarcely but the pressure indexes drop down from 0.43 to 0.40 under the pressure of 3-9 MPa. The hazard grades of propellants with 5% and 18% aluminum powder are 1.3 both. The impact and friction sensitivities of propellant with 18% aluminum powder are 0% and 44%, respectively, which are lower than the formulation with 5% aluminum powder (4% and 48%, respectively). At last, the calculation result shows that with the increase of aluminum powder, the energy and density of propellants grow up, but the standard specific impulse levels off to moderate pace of growth.

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引用本文

徐爽,汪越,武卓,等.铝粉含量对GAP钝感推进剂性能的影响[J].含能材料, 2021, 29(10):928-936. DOI:10.11943/CJEM2021071.
XU Shuang, WANG Yue, WU Zhuo, et al. Influence of Aluminum Powder Contents on Insensitive GAP Propellants[J]. Chinese Journal of Energetic Materials, 2021, 29(10):928-936. DOI:10.11943/CJEM2021071.

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历史
  • 收稿日期: 2021-04-02
  • 最后修改日期: 2021-08-10
  • 录用日期: 2021-05-26
  • 在线发布日期: 2021-07-20
  • 出版日期: 2021-10-25