CHINESE JOURNAL OF ENERGETIC MATERIALS
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GAP/NC基发射药的不敏感性能
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1.南京理工大学化学与化工学院, 江苏 南京 210094;2.泸州北方化学有限公司, 四川 泸州 646605

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Insensitivity Performance of GAP/NC-based Gun Propellants
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1.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology,Nanjing 210094, China;2.Luzhou North Chemical Industries Co., Ltd., Luzhou 646605, China

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    摘要:

    低敏感发射药的研究对于提高武器系统的生存能力和安全性能有重要的意义。以硝化棉(NC)和低感聚叠氮缩水甘油醚(GAP)为黏结剂、低感N-丁基硝氧乙基酰胺(Bu-NENA)为含能增塑剂、黑索今(RDX)为高能填料,石墨为导热助剂,制备了一种发射药(IM发射药)。对其理化、燃烧、力学和感度性能进行研究,通过慢速烤燃、快速烤燃、子弹撞击、破片撞击以及殉爆试验对该IM发射药的不敏感性能进行评估。结果表明,该IM发射药在定容燃烧下燃烧过程稳定,实测火药力为1050 kJ·kg-1,理论爆温为2677 K;-40 ℃下抗冲击强度和抗压强度分别为8.2 kJ·m-2和131.5 MPa;与太根发射药的感度相比(H50=16.33 cm,P=100%,V50=2.02 kV),IM发射药的撞击(H50=62.62 cm)、摩擦(P=28%)和静电感度(V50=1.95 kV)有明显降低;IM发射药在慢速烤燃、快速烤燃、子弹撞击、破片撞击以及殉爆试验中均未发生爆燃或爆炸,只发生燃烧反应,具有良好的不敏感性。

    Abstract:

    The research on low-sensitivity gun propellants has a vital impact on the survivability and safety performance of weapon system. Gun propellant (IM) with nitrocellulose (NC) and glycidyl azide polymer (GAP) as binder was prepared. N-butyl-N- nitramine (Bu-NENA) was used as low sensitive energetic plasticizer, hexogen (RDX) was used as high-energy filler and graphite as additive of thermal conductive. The physicochemical, combustion, mechanical, and sensitivity properties of the IM gun propellant were studied, and the insensitivity properties were further studied by slow cook-off, fast cook-off, bullet impact, fragment impact and sympathetic detonation tests. Results showed that the gun propellant had stable combustion performance, and the impetus was1050 kJ·kg-1. Theoretical explosion temperature was 2677 K. The impact strength and the compressive strength were 8.2 kJ·m-2 and 131.5 MPa at -40 ℃, respectively. The sensitivity of the gun propellant (H50=62.62 cm,P=28%,V50=1.95 kV) was greatly reduced compared with TEGN gun propellants(H50=16.33 cm,P=100%,V50=2.02 kV). Moreover, only combustion reactions were observed in slow cook-off, fast cook-off, bullet impact, fragment impact and sympathetic detonation tests. It demonstrated that the prepared gun propellants possessed good low vulnerability characteristics.

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引用本文

宋育芳,肖乐勤,李纯志,等. GAP/NC基发射药的不敏感性能[J].含能材料, 2023, 31(2):152-159. DOI:10.11943/CJEM2021301.
SONG Yu-fang, XIAO Le-qin, LI Chun-zhi, et al. Insensitivity Performance of GAP/NC-based Gun Propellants[J]. Chinese Journal of Energetic Materials, 2023, 31(2):152-159. DOI:10.11943/CJEM2021301.

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  • 收稿日期: 2021-11-13
  • 最后修改日期: 2022-07-25
  • 录用日期: 2022-05-27
  • 在线发布日期: 2022-07-22
  • 出版日期: 2023-02-25