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电控固体推进剂的点火、燃烧及熄灭特性研究进展
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国防科技大学 空天科学学院, 湖南 长沙 410073

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基金项目:

装备预研重点实验室基金项目(6142701200102);湖南省自然科学基金(2020JJ4665)


Research Progress on Ignition, Combustion and Extinction Characteristics of Electrically Controlled Solid Propellant
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College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China

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    摘要:

    电控固体推进剂(electrically controlled solid propellant,ECSP)具有多次点火和燃速可控的特性,可广泛应用于从微观到宏观的推进系统。本文总结了国内外以硝酸铵、硝酸羟胺和高氯酸盐为氧化剂的ECSP的研究概况,重点综述了硝酸羟胺基ECSP和高氯酸盐基ECSP点火、燃烧及熄灭特性的研究进展,分析了电压、压强以及金属添加剂对ECSP燃速调节的影响规律,并讨论了电能在ECSP点火和燃烧过程的作用机制。同时为未来深入研究ECSP点火、燃烧及熄灭机理提出参考建议:开展ECSP固相和气相化学反应机理研究,建立点火、燃烧及熄灭模型和反应机理框架;系统研究电极排布和电极构型对ECSP燃烧效率的影响以及ECSP配方与导电性能之间的关系,寻求改善电极和推进剂界面电阻的方法。优选高性能ECSP配方,完善ECSP燃烧反应机理及燃速调节机制,提高ECSP压强阈值,是电控固体火箭发动机设计、应用和性能调控的关键。

    Abstract:

    Electrically controlled solid propellant (ECSP) has the characteristics of multiple ignitions and controllable burning rate, and can be widely used in propulsion systems from micro to macro. The research on ECSP with ammonium nitrate, hydroxylamine nitrate and perchlorate as oxidants was summarized at home and abroad, especially the characteristics of ignition, combustion and extinction for ECSP based on hydroxylamine nitrate and perchlorate were emphatically reviewed. Meanwhile, the effects of voltage, pressure and metal additives on the burning rate adjustment of ECSP were analyzed, and the mechanism of electric energy in the ignition and combustion process of ECSP was discussed. Furthermore, some suggestions were put forward for further in-depth study on the ignition, combustion and extinction mechanism of ECSP: study the chemical reaction mechanism on the solid and gas phases of ECSP, establish the model and framework of the reaction mechanism for ignition, combustion and extinction; explore the effect of electrode arrangement and electrode configuration on the combustion efficiency of ECSP and the relationship between ECSP formula and electrical conductivity systematically, and seek the method to decrease the interface resistance between electrode and propellant. Finally, optimizing the formulation of high-performance ECSP, perfecting the combustion reaction mechanism and burning rate adjustment mechanism of ECSP, and raising the pressure threshold of ECSP are the keys to the design, application and performance regulation of electronically controlled solid rocket motor.

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引用本文

李洋,夏智勋,马立坤,等.电控固体推进剂的点火、燃烧及熄灭特性研究进展[J].含能材料, 2023, 31(9):931-948. DOI:10.11943/CJEM2023018.
LI Yang, XIA Zhi-xun, MA Li-kun, et al. Research Progress on Ignition, Combustion and Extinction Characteristics of Electrically Controlled Solid Propellant[J]. Chinese Journal of Energetic Materials, 2023, 31(9):931-948. DOI:10.11943/CJEM2023018.

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  • 收稿日期: 2023-02-10
  • 最后修改日期: 2023-09-04
  • 录用日期: 2023-07-03
  • 在线发布日期: 2023-09-01
  • 出版日期: 2023-09-25