CHINESE JOURNAL OF ENERGETIC MATERIALS
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BGAP的合成与展望
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1.黎明化工研究设计院有限责任公司, 河南 洛阳 471000;2.西南科技大学分析测试中心, 四川 绵阳 621000

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Research Progress and Prospect of Branched Glycidyl Azide Polymer
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Affiliation:

1.Liming Research & Design Institute of Chemical Industry Co., Ltd., Luoyang 471000, China;2.Analysis and Test Center, Southwest University of Science and Technology, Mianyang 621000, China

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    摘要:

    含支化结构的聚叠氮缩水甘油醚(BGAP)含能黏合剂比线型聚叠氮缩水甘油醚(GAP)含能黏合剂具有更高的相对分子质量、更宽的官能度(f)调节范围、更高的生成热、更低的黏度等,能够提高复合固体推进剂的能量水平以及改进其工艺性能和力学性能,是叠氮黏合剂的重要研究方向之一。如何可控调节官能度、相对分子质量及其分布等重要结构参数,成为获得高质量BGAP含能黏合剂的关键。本文详细阐述了BGAP的一步裂解叠氮化法合成工艺并提出了可能的合成机理,介绍了BGAP的性能研究现状,分析了存在的问题和不足,展望了BGAP的合成和性能研究发展方向,强调优化BGAP的后处理工艺、提高BGAP的制备能力以及加强BGAP的基础性能和应用研究是今后研究的重点。

    Abstract:

    Branched glycidyl azide polymer (BGAP) has higher relative molecular mass, wider adjustment range of hydroxyl functionality (f), higher heat of formation and lower viscosity than linear glycidyl azide polymer (GAP). It can increase the energy level, and improve the processing and mechanical properties of the composite solid propellant. Therefore it has become a hot research topic in the field of the azido polyether binder. However, the essentially important key to obtain high quality BGAP energetic binder is how to control and regulate some structural parameters such as hydroxyl functionality, molecular weight and molecular weight distribution. This paper illustrates two synthetic methods and processes of BGAP, proposes the possible reaction mechanism, and summarizes the progress in performance research. Some problems and deficiencies are pointed out. Finally, the development prospects of BGAP in the field of synthesis and performance research are forecasted. It is concluded that optimizing the extraction procedure after reaction, improving the throughput per run, and strengthening the studies in fundamental performance and application will be the focuses in future researches.

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引用本文

闫镒腾,孙善虎,刘杉,等. BGAP的合成与展望[J]. 含能材料,DOI:10.11943/CJEM2023262.

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  • 收稿日期: 2023-12-13
  • 最后修改日期: 2024-03-25
  • 录用日期: 2024-04-07
  • 在线发布日期: 2024-04-08
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