The synthesis method of high molecular weight glycidyl azide polymer (HL-GAP) is described. The experimental results indicate that the azidation of the precursor,polyepichlorohydrin (PECH),is always accompanied with its chain-breaking. In order to prepare high molecular weight and high azidized product,the influence of catalyst,antioxydant,inert gas protection and other factors on the HL-GAP molecular weight (Mw) and its distribution were experimentally investigated. After optimization of the above said factors,the Mw of HL-GAP was increased to 1.5×105 and 2.95×105 with azidation rate (Ra) of 99.16% and 69.20%,respectively,much higher than Vandenberg′s report in USP 3 645 917 (Mw=5×104,Ra=49%).
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王平,夏中均,尹莉莎,等.高分子量线型叠氮缩水甘油醚聚合物的合成[J].含能材料, 1998, 6(3):102-106. Wang Ping, Xia Zhong-jun, Yin Li-sa, et al. SYNTHESIS OF HIGH MOLECULAR WEIGHT GLYCIDYL AZIDE POLYMER[J]. Chinese Journal of Energetic Materials, 1998, 6(3):102-106.