CHINESE JOURNAL OF ENERGETIC MATERIALS
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N,N′-二(硝基呋咱基)草酰胺的合成及性能
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李战雄(1970-),男,博士,现从事有机化学研究,发表论文10余篇。

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Synthesis and Properties of N,N′-Di(nitrofurazano)oxalamide
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    以3,4-二氨基呋咱为原料经酰化合成出N,N′-二(硝基呋咱基)草酰胺(DNFOA)。利用 IR,1HNMR , MS和元素分析对其结构进行了鉴定。用悬浮法测定DNFOA密度为1.90 g·cm-3, 计算其标准生成焓为303.6 kJ·mol-1,爆速8 559.6 m·s-1, 爆压33.6 GPa。DNFOA的撞击感度为82 cm(H50, 5 kg落锤)。

    Abstract:

    N,N′-di(nitrofurazano)oxalamide (DNFOA) was synthesized from 3,4-diaminofurazan by acidylating. The structure of DNFOA has been identified by IR,1HNMR,MS and elemental analysis. The density of DNFOA was determined to be 1.90 g·cm-3 by suspension method. The values of the standard enthalpy,the detonation velocity and the explosive pressure at C-J point were calculated to be 303.6 kJ·mol-1,8 559.6 m·s-1,33.6 GPa, respectively. As a low-sensitivity high energetic density compound,the impact-sensitivity (H50) of DNFOA was mensurated to be 82 cm(5 kg drop hammer).

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李战雄,欧育湘,陈博仁. N, N′-二(硝基呋咱基)草酰胺的合成及性能[J].含能材料, 2002, 10(1):10-12.
LI Zhan-xiong, OU Yu-xiang, CHEN Bo-ren. Synthesis and Properties of N, N′-Di(nitrofurazano)oxalamide[J]. Chinese Journal of Energetic Materials, 2002, 10(1):10-12.

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  • 收稿日期: 2001-05-17
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  • 在线发布日期: 2011-11-02
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