Diisobutyl aluminum chloride is synthesized by the reaction of triisobutyl aluminum and carbon tetrachloride. Diisobutyl aluminum azide (DBAA) is synthesized by the reaction of the sodium azide and diisobutyl aluminum chloride in arenes, and its complex(DBAA·THF) is also synthesized through the reaction of the sodium azide and diisobutyl aluminum chloride in tetrahydrofuran. DBAA and DBAA·THF are characterized by IR and HNMR spectrum. The properties of DBAA and DBAA·THF are also studied.
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高占先,冯立春,张小航.叠氮二异丁基铝及其配合物的制备与表征[J].含能材料, 2002, 10(3):108-111. GAO Zhan-xian, FENG Li-chun, ZHANG Xiao-hang. Synthesis and Characterization of Diisobutyl Aluminum Azide and its Complex[J]. Chinese Journal of Energetic Materials, 2002, 10(3):108-111.