CHINESE JOURNAL OF ENERGETIC MATERIALS
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乳化剂对B炸药中蜡的分散与乳化研究
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王丽琼(1959-),女,副教授,主要从事军事化学与烟火技术研究和教学。e-mail: nkles@bit.edu.cn

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国家自然科学基金(10276006)和爆炸灾害预防、控制国家重点实验室开放基金(KFJJ2001)资助


Research on Dispersion and Emulsification of Wax Caused by Emulsifier in Composition B
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    摘要:

    采用乳化及稳定性实验方法和正交偏光显微镜手段,分析对比了聚乙烯吡咯烷酮类、卵磷脂类两种乳化剂对B炸药中蜡的分散效果,认为带有较大烷基支链的聚乙烯吡咯烷酮类乳化剂可有效降低蜡的表面张力,使蜡以均匀小蜡滴形式分散在熔融B炸药中; 卵磷脂与NC组成的复合乳化剂能够较好地分散B炸药中的蜡,且不发生变色现象。

    Abstract:

    By experiments of emulsification stability and observation of microscope photographs,effects of two kinds of emulsifier polyvinylpyrrolidone and lecithin on dispersion of wax in composition B were studied. It is concluded that polyvinylpyrrolidone can decrease surface tension of wax effectively and disperse wax in melting composition B in small wax drop,but make color of the system darken. While adding lecithin in the system,change of the color isn′t obvious,but stability time of the system is shorter. However,the mixture composed of lecithin and NC is a good complex emulsifier for dispersing wax in composition B and doesn′t result in color change of the system. The differences between microstructures without emulsifier,with single emulsifier and with complex emulsifier are given in this paper.

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王丽琼,曾庆国,王晓宁,等.乳化剂对B炸药中蜡的分散与乳化研究[J].含能材料, 2004, 12(5):264-268.
WANG Li-qiong, ZENG Qing-guo, WANG Xiao-ning, et al. Research on Dispersion and Emulsification of Wax Caused by Emulsifier in Composition B[J]. Chinese Journal of Energetic Materials, 2004, 12(5):264-268.

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  • 收稿日期: 2004-04-01
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  • 在线发布日期: 2011-11-03
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