CHINESE JOURNAL OF ENERGETIC MATERIALS
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海因/三嗪类复合键合剂包覆黑索今的研究
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李江存(1980-),女,在读博士,主要从事含能药剂与材料化学研究。e-mail: ljc@bit.edu.cn

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RDX Coated with Hyantoin/Triazines Composite Bonding Agent
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    采用水-溶液悬浮法,对海因/三嗪类复合键合剂包覆RDX进行了实验研究。通过L9(34)正交实验研究了反应时间、反应温度、键合剂用量和搅拌速度对包覆度的影响规律,并利用X射线光电子能谱(XPS )、扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)、差示扫描量热法(DSC)、感度实验等对包覆后的RDX进行表征。正交实验确定的最佳包覆条件: 10 g RDX,反应时间90 min,反应温度50 ℃,键合剂用量0.3 g, 搅拌速度700 r·min-1,包覆度达87%。包覆后RDX表面明亮有光泽,包覆厚度约为0.2 μm。红外光谱中NO2基团的吸收峰红移22 cm-1至1510 cm-1,且吸收带展宽。热分解峰温升高0.4 ℃,撞击感度特性落高提高4.5 cm。

    Abstract:

    RDX was coated with hyantoin/triazines composite bonding agent and the effects of the processing parameters,including reaction time, reaction temperature and bonding agent mass on the coating degree were studied by means of water-solution suspending method in the L9(34) orthogonal experiment. The coated RDX was characterized by X-ray photoelectron spectroscopy(XPS), scanning electron microscope(SEM), Fourier transform infrared spectroscopy(FTIR), differential scanning calorimetry(DSC) and impact sensitivity (H50). The optimum conditions are as follows: 10.0 g RDX, reaction time 90 min,reaction temperature 50 ℃, 0.3 g composite bonding agent (CBA), and stirring speed 700 r·min-1. Accordingly,coating degree is up to 87%. It is found that surface of the coated RDX is covered by clear film with a thickness of about 0.2 μm. In FTIR spectra, NO2 group absorption peak has a 22 cm-1 red shift to 1510 cm-1and the absorption band widened. Thermal decomposition peak temperature is enhanced 0.4 ℃. The characteristic height of impact sensitivity (H50) is increased by 4.5 cm.

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李江存,焦清介,任慧,等.海因/三嗪类复合键合剂包覆黑索今的研究[J].含能材料, 2008, 16(1):56-59.
LI Jiang-cun, JIAO Qing-jie, REN Hui, et al. RDX Coated with Hyantoin/Triazines Composite Bonding Agent[J]. Chinese Journal of Energetic Materials, 2008, 16(1):56-59.

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  • 收稿日期: 2007-05-31
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  • 在线发布日期: 2011-05-06
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