CHINESE JOURNAL OF ENERGETIC MATERIALS
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二茂铁氮杂环衍生物的合成及对高氯酸铵热分解的催化作用
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高勇(1977-),男,博士后,从事功能分子的设计与合成研究。email: gaoyong77@126.com

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福建省自然科学基金资助(2009J05023; 2009J05028)


Synthesis of Ferrocenyl Dihydropyrazole Derivatives and their Catalysis on Thermal Decomposition of AP
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    摘要:

    设计合成了三个含有极性基团的二茂铁氮杂环衍生物,通过1H NMR、FT-IR和质谱对目标产物进行了结构表征。利用差热分析(DTA)和热重(TG)研究了在高氯酸铵(AP)中分别添加5%目标化合物后的热分解性能,发现添加二茂铁氮杂环衍生物后,AP的第二个放热峰温度可提前89.10 ℃,两个放热峰的距离可缩小至25.82 ℃。

    Abstract:

    Three ferrocenyl nitrogenous heterocyclic compounds containing polar functionalities were designed and synthesized,and their structures were characterized by 1H NMR,IR and MS spectra. The thermal decomposition properties of AP with 5% (weight) of the titled compounds were investigated by differential thermalanalysis (DTA) and thermogravimetry (TG). Results show that the second exothermic peak temperature of AP is reduced by 89.10 ℃ and the temperature difference between the two exothermic peaks can be reduced to 25.82 ℃.

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高勇,柯成锋,李恒东,等.二茂铁氮杂环衍生物的合成及对高氯酸铵热分解的催化作用[J].含能材料, 2011, 19(1):19-22. DOI:10.3969/j. issn.1006-9941.2011.01.005.
GAO Yong, KE Chen-feng, LI Heng-dong, et al. Synthesis of Ferrocenyl Dihydropyrazole Derivatives and their Catalysis on Thermal Decomposition of AP[J]. Chinese Journal of Energetic Materials, 2011, 19(1):19-22. DOI:10.3969/j. issn.1006-9941.2011.01.005.

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  • 收稿日期: 2010-03-03
  • 最后修改日期: 2010-04-15
  • 录用日期: 2010-04-19
  • 在线发布日期: 2012-02-22
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