CHINESE JOURNAL OF ENERGETIC MATERIALS
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RDX晶体特性对冲击感度的影响规律
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李洪珍(1971-),女,副研究员,硕士,主要从事炸药合成与结晶。email: happyhongzhen@163.com

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国家安全重大基础研究项目(No. 613830102)


Effects of RDX Crystal Characteristics on Shock Sensitivities
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    摘要:

    采用标准隔板和落锤撞击试验方法分别研究了RDX的晶体内部空隙(用晶体表观密度表征)、颗粒度和形貌对包括冲击波感度和撞击感度在内的冲击感度的影响规律。冲击波感度测试采用隔板试验,药柱配方为RDX/食用油 (质量比为76/24),药柱采用液体填充方式制备。隔板试验研究表明: 随着RDX晶体表观密度在1.7961~1.7983 g·cm-3范围内增加,炸药配方的冲击波感度降低,隔板厚度从14 mm 降到12.2 mm,晶体表观密度与隔板厚度基本成线性关系; 当晶体表观密度为1.7976 g·cm-3时,在50~600 μm粒度范围内,随着颗粒度的增加,RDX炸药配方的冲击波感度降低,隔板厚度从13.5 mm 降到12.3 mm; 当晶体表观密度和颗粒度相近时,晶体颗粒的外观形貌对炸药冲击波感度影响不大。落锤撞击试验表明: RDX颗粒度对撞击感度影响较大,当平均颗粒直径在16.7~337.9 μm范围时,随着粒径的增加,特性落高从75 cm降到35.8 cm,颗粒越大撞击感度越高; 当颗粒度相近时,在1.7961~1.7983 g·cm-3范围内,RDX晶体表观密度对撞击感度几乎无影响。

    Abstract:

    Effects of RDX crystal characteristics including crystal internal porosity,particle size and distribution on shock sensitivities were studied by applying a method that RDX particles immersed in rap oil which excluded effects on shock sensitivity of binder/crystal interface,binder porosity and crystal shape. The shock initiation threshold of RDX/rap oil (mass ratio 76/24) compostion was determind with gap test where RDX was recrystallized to various qualities. Results show that the gap thickness decreases from 14.0 mm to 12.2 mm when the crystal apparent density increases from 1.7961 g·cm-3 to 1.7983 g·cm-3,and gap thickness decreases from 13.5 mm to 12.3 mm with increasing of particle size at the range of 50-600 μm,and this shows that crystal apparent density and particle size are two important factors affecting shock sensitivity. Impact sensitivity of RDX powder by drop weight apparatus was also studied. The test shows that drop weight impact sensitivity decreases from 75 cm to 35.8 cm evidently when particle average size increases from 16.7 μm to 337.9 μm,and does not almost vary while crystal apparent density changing at 1.7961-1.7983 g·cm-3,which demonstrates that particle size is the important factor affecting impact sensitivity.

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李洪珍,康彬,李金山,等. RDX晶体特性对冲击感度的影响规律[J].含能材料, 2010, 18(5):487-491. DOI:10.3969/j. issn.1006-9941.2010.05.002.
LI Hong-zhen, KANG Bin, LI Jin-shan, et al. Effects of RDX Crystal Characteristics on Shock Sensitivities[J]. Chinese Journal of Energetic Materials, 2010, 18(5):487-491. DOI:10.3969/j. issn.1006-9941.2010.05.002.

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  • 收稿日期: 2010-06-09
  • 最后修改日期: 2010-07-09
  • 录用日期: 2010-07-13
  • 在线发布日期: 2012-02-22
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