CHINESE JOURNAL OF ENERGETIC MATERIALS
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浇铸无烟CMDB推进剂流变性能
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西安近代化学研究所,西安近代化学研究所

作者简介:

蔚红建(1969-),男,博士研究生,高级工程师,从事固体推进剂研究。

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Rheological Properties of Cast Smokeless CMDB Propellants
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Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute

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    摘要:

    为有效调节改性双基(CMDB)推进剂(主要组分为硝化棉、硝化甘油和黑索今)的流变性能,利用HAAKE旋转流变仪研究了增塑剂、高分子增稠剂及温度对CMDB推进剂流变特性的影响。结果表明,CMDB推进剂为具有屈服应力的假塑性流体,调整增塑剂硝化甘油与吉纳的比例(m(NG):m(DINA)=10:1,8:1,6:1),当增塑剂比例降低,CMDB推进剂粘度和屈服值增大,流动活化能减小;高分子增稠剂含量增加,CMDB推进剂粘度明显增大,流动活化能减小;温度升高,CMDB推进剂粘度减小。

    Abstract:

    In order to regulate the rheological properties of cast smokeless composite modified double based (CMDB) propellants composed of nitrocellulose, nitroglycerin and clotrimethylene-trinitramine, the influences of plasticizer, rheological modifier and temperature on the rheological properties of cast CMDB propellants were studied by a HAAKE rotational viscometer. The results show that CMDB propellants are pseudoplastic fluid with yield stress. By adjusting the ratio between plasticizer nitroglycerin and DINA (m(NG):m(DINA)=10:1, 8:1, 6:1), with specific plasticizer reduces, the viscosity and yield of CMDB propellants increase and the flow activation energy decreases. With the increasing in rheological modifier content, the viscosity of CMDB propellants increases obviously, and the flow activation energy decreases. The viscosity of CMDB propellants decreases at higher temperatures.

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蔚红建,樊学忠,付小龙,等.浇铸无烟CMDB推进剂流变性能[J].含能材料, 2012, 20(1):71-75. DOI:10.3969/j. issn.1006-9941.2012.01.017.
YU Hong-jian, FAN Xue-zhong, FU Xiao-long, et al. Rheological Properties of Cast Smokeless CMDB Propellants[J]. Chinese Journal of Energetic Materials, 2012, 20(1):71-75. DOI:10.3969/j. issn.1006-9941.2012.01.017.

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历史
  • 收稿日期: 2010-09-10
  • 最后修改日期: 2011-07-08
  • 录用日期: 2011-07-21
  • 在线发布日期: 2012-02-23
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