CHINESE JOURNAL OF ENERGETIC MATERIALS
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硅系延期药的共沉淀法制备及其性能
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北京理工大学机电学院,北京理工大学机电学院

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任庆国(1987-),男,在读研究生,军事化学与烟火技术。

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总装备部项目(51305120302)


Co-precipitation and Properties of Silicon Delay Composition
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School of Mechatronical Engineering, Beijing Institute of Technology,School of Mechatronical Engineering, Beijing Institute of Technology

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    摘要:

    采用共沉淀法和手工混药法制备了硅系延期药,通过扫描电子显微镜(SEM)、能谱分析(EDS)及X-射线粉末衍射(XRD)分析显示:在共沉淀过程中有BaSO4和(BaPb)SO4的生成,并实现了对硅粉Si和Pb3O4的部分包覆。在60 MPa压力下将一定量延期药和适量点火药装入外径为5 mm的铁制延期管内,采用光电法对延期时间进行测试,结果表明:共沉淀法制备的延期药的平均燃速为1.25 mm·s-1,手工混合制备的延期药的平均燃速为1.41 mm·s-1; 共沉淀法制备的延期药的延期精度明显高于手工混制的,前者燃速的标准差0.073,后者的为0.25。

    Abstract:

    The silicon type delay composition was prepared by co-precipitation and hand-mixed.Based on the analysis of electron microscopy, EDS spectra and X-ray diffraction, BaSO4 and little (BaPb) SO4 were found out and part of silicon and Pb3O4 were coated by BaSO4 during the process of co-precipitation. The delay time and burning rate of the delay compositions were measured by light-sensitive detector. Results show that the average burning rate of the delay composition prepared by co-precipitation is 1.25 mm·s-1, slower than that of hand-mixed, which is 1.41 mm·s-1. The delay precision of the delay composition prepared by co-precipitation was better than that of hand-mixed one. The standard deviation of burning rate of the co-precipitation composition is 0.073, and that of the composition prepared by hand-mixed is 0.25.

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任庆国,乔小晶.硅系延期药的共沉淀法制备及其性能[J].含能材料, 2012, 20(4):409-413. DOI:10.3969/j. issn.1006-9941.2012.04.006.
REN Qing-guo, Qiao Xiao-jing. Co-precipitation and Properties of Silicon Delay Composition[J]. Chinese Journal of Energetic Materials, 2012, 20(4):409-413. DOI:10.3969/j. issn.1006-9941.2012.04.006.

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  • 收稿日期: 2011-09-09
  • 最后修改日期: 2012-05-24
  • 录用日期: 2012-02-27
  • 在线发布日期: 2012-07-26
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