CHINESE JOURNAL OF ENERGETIC MATERIALS
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环氧树脂和石墨对高氯酸钾类烟火药撞击感度的影响
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沈阳理工大学装备工程学院,沈阳理工大学装备工程学院,沈阳理工大学装备工程学院,沈阳理工大学装备工程学院

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郝清伟(1963-),男,工程师,从事烟火特种效应测试系统的研发。

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Effects of Epoxy Resin and Graphite on Impact Sensitivity of KClO4-type Pyrotechnics Composite
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shenyang ligong university,Shenyang Ligong University,Shenyang Ligong University,Shenyang Ligong University

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    摘要:

    为了揭示高氯酸钾类烟火药的安全性,制备了本工作称为样品1#~7#的7种50/50/m/n-KClO4/Al/环氧树脂/石墨混合物体系(m=n=0;m=3,n=0;m=5,n=0;m=5,n=1;m=5, n=2;m=5,n=3;m=5, n=4)。用GJB772A-1997-601.1,热重-差热分析(TG-DTA)和扫描电子显微镜(SEM)研究了环氧树脂和石墨对高氯酸钾类烟火药撞击感度的影响。结果表明:样品1#~7#的撞击感度爆炸百分数分别为0,60,76,40,12,2和0。与样品1#比较,样品1#中加入环氧树脂使样品2#和3#的撞击感度爆炸百分数升高,且随样品1#中环氧树脂含量的增加,撞击感度爆炸百分数升高。与样品3#比较,样品3#中加入石墨使样品4#~7#的撞击感度爆炸百分数降低,且随样品3#中石墨含量的增加,撞击感度爆炸百分数以4#>5#>6#>7#次序降低。探讨了环氧树脂对KClO4/Al二元体系起增感作用和石墨起减感作用的原因。

    Abstract:

    To expose the safety of KClO4-type pyrotechnics composite, seven 50/50/m/n-KClO4/Al/epoxy resin/graphite mixture systems(m=n=0; m=3, n=0; m=5, n=0; m=5, n=1; m=5, n=2; m=5, n=3; m=5, n=4) known as samples 1#-7# in this work were prepared, respectively. The effects of epoxy resin and graphite on the impact sensitivity of KClO4-type pyrotechnics composite were studied by standard method GJB772A-1997-601.1, TG-DTA and SEM. The results show that the explosion percent of impact sensitivity for samples 1#-7# is 0, 60, 76, 40, 12, 2 and 0, respectively. In comparison with sample 1#, adding epoxy resin in samples 1# makes the explosion percent of impact sensitivity of samples 2# and 3# enhance and with increasing the amount of epoxy resin in samples 3#, the explosion percent of impact sensitivity increases. In comparison with sample 3#, the addition of graphite into samples 4# makes the explosion percent of impact sensitivity of samples 4#-7# decreases and with increasing the amount of graphite in samples 3#, the explosion percent of impact sensitivity decreases in the order 4#>5#>6#>7#. The reasons of sensitization of epoxy resin and desensitization of graphite to the KClO4-Al binary system are discussed.

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引用本文

郝清伟,霸书红,孙振兴,等.环氧树脂和石墨对高氯酸钾类烟火药撞击感度的影响[J].含能材料, 2012, 20(3):302-305. DOI:10.3969/j. issn.1006-9941.2012.03.008.
HAO Qing-wei, BA Shu-hong, SUN Zhen-xing, et al. Effects of Epoxy Resin and Graphite on Impact Sensitivity of KClO4-type Pyrotechnics Composite[J]. Chinese Journal of Energetic Materials, 2012, 20(3):302-305. DOI:10.3969/j. issn.1006-9941.2012.03.008.

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  • 收稿日期: 2011-09-21
  • 最后修改日期: 2011-11-30
  • 录用日期: 2011-12-12
  • 在线发布日期: 2012-06-01
  • 出版日期: