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精制对5,7-二氨基-4,6-二硝基苯并氧化呋咱性能的影响
作者:
作者单位:

(南京理工大学化工学院, 江苏 南京 210094)

作者简介:

董岩(1983-),男,博士研究生,主要从事含能材料合成与性能研究。e-mail: 627310@163.com

通讯作者:

刘祖亮(1951-),男,教授,主要从事含能材料和精细化工中间体研究。e-mail: liuzl@mail.njust.edu.cn

基金项目:


Effect of Refining on the Properties of 5,7-Diamino-4,6-dinitrobenzenfuroxan
Author:
Affiliation:

(School of Chemical Engineering, NUST, Nanjing 210094, China)

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    摘要:

    为研究5, 7-二氨基-4, 6-二硝基苯并氧化呋咱(CL-14)的性能, 经CL-14钾盐重结晶, 高温酸化, 加热下除酸, 精制了CL-14。按GJB772A-1997标准化方法测试了精制前后样品的感度和热安定性。用DSC方法测试了其放热分解反应温度。结果表明, 精制CL-14的pH值为6.5。撞击感度和摩擦感度分别为24%和16%。200 ℃真空安定性试验48 h放气量为0.81 mL·g-1。DSC放热分解反应峰温度为313.7 ℃, 比精制前提高13.7 ℃, 说明, 精制后的CL-14有较低的酸度和良好的热安定性。

    Abstract:

    In order to study the properties of 5, 7-diamino -4, 6-dinitrobenzenfuroxan(CL-14), CL-14 was refined via recrystallization of potassium salt of CL-14, acidification at high temperature and acid elimination under heating. The sensitivity and thermal stability of unrefined CL-14 and refined CL-14 were tested by the standardization method GJB772A-1997. The peak temperature of exothermic decomposition reaction of unrefined CL-14 and refined CL-14 was determined by DSC. Results show that the pH of refined CL-14 is 6.5. The impact sensitivity and friction sensitivity are 24% and 16% respectively. The amount of gas evolved of refined CL-14 obtained by Vacuum Stability Test with 200 ℃/48 h is 0.81 mL·g-1.The peak temperature of exothermic decomposition reaction of refined CL-14 is 313.7 ℃, 13.7 ℃ higher than that of the unrefined CL-14, showing that the refined CL-14 has lower acidity and better thermal stability.

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董岩,刘祖亮.精制对5,7-二氨基-4,6-二硝基苯并氧化呋咱性能的影响[J].含能材料, 2013, 21(6):706-710. DOI:10.3969/j. issn.1006-9941.2013.06.003.
DONG Yan, LIU Zu-liang. Effect of Refining on the Properties of 5,7-Diamino-4,6-dinitrobenzenfuroxan[J]. Chinese Journal of Energetic Materials, 2013, 21(6):706-710. DOI:10.3969/j. issn.1006-9941.2013.06.003.

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历史
  • 收稿日期: 2012-12-24
  • 最后修改日期: 2013-02-07
  • 录用日期: 2013-04-09
  • 在线发布日期: 2013-12-06
  • 出版日期: