CHINESE JOURNAL OF ENERGETIC MATERIALS
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硝酸酯液体推进剂长时储存性能
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作者单位:

(西安近代化学研究所, 陕西 西安 710065)

作者简介:

贾林(1970-),女,高级工程师,主要从事火炸药分析检测研究。e-mail: 1169855351@qq.com 通信联系人: 张林军(1976-),男,高级工程师,主要从事危险品环境适应性及寿命评估技术研究。e-mail: zhanglj204@163.com

通讯作者:

张林军(1976-),男,高级工程师,主要从事危险品环境适应性及寿命评估技术研究。e-mail: zhanglj204@163.com

基金项目:

国防计量项目(J092010B001)


Performance of a Notric Acid Ester Liquid Propellant at Long-term Storage
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Affiliation:

(Xi′an Modern Chemistry Research Institute, Xi′an 710065, China)

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    摘要:

    通过热加速老化、自然存储、湿热环境金属相容性(腐蚀性)试验, 研究了一种硝酸酯液体推进剂(OTTO-II)的长储性能。结果表明:按温度系数法, OTTO-II常温(30 ℃)下的预测安全贮存寿命不少于11 a; 自然环境下贮存2.4 a各组分无明显变化; 在60 ℃、85%RH环境下储存30 d产品中的H2O含量达到饱和, 但硝酸酯和安定剂含量未变。在(60 ℃、85%RH、30 d)温湿条件下, 6种不同表面加工工艺的镁金属试片均不被OTTO-II腐蚀; 仅个别镁金属试片可能因表面加工工艺不当, 对丙二醇二硝酸酯(PGDN)的分解产生一定的促进作用。

    Abstract:

    The long-term storage properties of a notric acid ester (OTTO-II) were investigated by elevated-temperature aging test, natural environment storage test, hydrothermal environment metal compatibility (causticity) test. Results show that its safe storage life estimated at 30 ℃ is not less than 11 a and its ingredients unchanged after stored for 2.4 a under the natural environment. The water in OTTO-II is saturation after storied under the hydrothermal environment conditions of 60 ℃, 85%RH, and 30 d, but the content of the stabilizer and notric acid ester is stable. The magnesium flakes in the hydrothermal environmental, machined by 6 different ways, are not corroded by OTTO-II. Only one flake catalyzes the decomposition of PGDN because of unsuitable machining technique for metal surface.

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引用本文

贾林,韩芳,李燕,等.硝酸酯液体推进剂长时储存性能[J].含能材料, 2014, 22(2):165-169. DOI:10.3969/j. issn.1006-9941.2014.02.008.
JIA Lin, HAN Fang, LI Yan, et al. Performance of a Notric Acid Ester Liquid Propellant at Long-term Storage[J]. Chinese Journal of Energetic Materials, 2014, 22(2):165-169. DOI:10.3969/j. issn.1006-9941.2014.02.008.

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历史
  • 收稿日期: 2013-09-11
  • 最后修改日期: 2013-12-09
  • 录用日期: 2013-12-16
  • 在线发布日期: 2014-04-28
  • 出版日期: 2014-04-24