CHINESE JOURNAL OF ENERGETIC MATERIALS
+高级检索
AP/HTPB老化复合底排推进剂热物性实验研究
作者:
作者单位:

(1. 南京理工大学能源与动力工程学院, 江苏 南京 210094; 2. 中国航天科工第六研究院41所, 内蒙古 呼和浩特 010010)

作者简介:

张领科(1978-),男,副研究员,主要从事现代火炮高效发射技术,含能材料稳燃控制技术的研究。e-mail: nustzlk@126.com

通讯作者:

基金项目:

国家自然科学基金资助(51106075)


Experimental Study of Thermal Physical Property of Aged AP/HTPB Composite Base Bleed Propellant
Author:
Affiliation:

(1. Nanjing University of Science & Technology,Nanjing 210094, China; 2. 41st Branch of Sixth Research Institute of Aerospace Industry and Technology, Huhehaote 010010, China)

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
    摘要:

    为研究底排装置内底排药剂点火燃烧特性并提高数值计算准确性, 用差示扫描量热仪(DSC)和热导仪对比研究了某155 mm底排弹用未老化和经自然老化(在密封塑料袋内室温保存20余年)的高氯酸铵(AP)/端羟基聚丁二烯(HTPB)底排药剂的比热容和导热系数。结果表明, 老化底排药剂20 ℃·min-1升温时DSC曲线的最大吸热峰温度和最大放热峰温度分别为253.52 ℃和437.54 ℃。基于DSC曲线和多项式拟合法得到了40~180 ℃温区间的比热容与温度的依变关系。老化底排药剂的比热容平均值和导热系数分别为0.9868 kJ·kg-1·℃-1和0.2292 W·m-1·K-1。未老化底排药剂的比热容平均值和导热系数分别为0.8887 kJ·kg-1·℃-1和0.4020 W·m-1·K-1。与未老化药剂相比, 老化药剂的比热容增大约11%,而导热系数减小约43%。

    Abstract:

    To research the ignition and combustion characteristics of base bleed propellant in the base bleed unit and improve the accuracy of numerical simulation, the specific heat capacity and conductivity coefficient for unaged and naturally aged (stored in a sealed plastic bag under room temperature) AP/HTPB base bleed propellant used in a 155mm base bleed projectile were determined by differential scanning calorimeter (DSC) and conductometer, respectively. Results show that the maximum endothermic peak temperature and the maximum exothermlic peak temperature on DSC curve of the aged base bleed propellant at a heating rate of 20 ℃·min-1 are 253.52 ℃ and 437.54 ℃, respectively. The function of specific heat capacity as temperature with in 40-180 ℃ is obtained based on DSC curves by polynomial fitting method. The average specific heat capacity and conductivity coefficient are 0.9868 kJ·kg-1·℃-1 and 0.2292 W·m-1·K-1 for the aged base bleed propellant and 0.8887 kJ·kg-1·℃-1and 0.4020 W·m-1·K-1 for unaged base bleed propellant, respectively. In comparison with unaged base bleed propellant, the average specific heat capacity of aged base bleed propellant increases about 11%, whereas conductivity coefficient of aged bleed propellant decreases about 43%.

    参考文献
    相似文献
    引证文献
文章指标
  • PDF下载次数:
  • HTML阅读次数:
  • 摘要点击次数:
  • 引用次数:
引用本文

张领科,赵威,余永刚. AP/HTPB老化复合底排推进剂热物性实验研究[J].含能材料, 2014, 22(5):669-673. DOI:10.3969/j. issn.1006-9941.2014.05.017.
ZHANG Ling-ke, ZHAP Wei, YU Yong-gang. Experimental Study of Thermal Physical Property of Aged AP/HTPB Composite Base Bleed Propellant[J]. Chinese Journal of Energetic Materials, 2014, 22(5):669-673. DOI:10.3969/j. issn.1006-9941.2014.05.017.

复制
历史
  • 收稿日期: 2013-11-27
  • 最后修改日期: 2014-01-10
  • 录用日期: 2014-02-24
  • 在线发布日期: 2014-10-29
  • 出版日期: