CHINESE JOURNAL OF ENERGETIC MATERIALS
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结构试验器固体推进剂装药低温加速老化试验研究
作者:
作者单位:

(1. 中国空空导弹研究院, 河南 洛阳 471009; 2. 空军驻包头地区军代室, 内蒙古 呼和浩特 010010; 3. 航天科工六院46所, 内蒙古 呼和浩特 010010)

作者简介:

曹付齐(1966-),男,高级工程师,研究方向是固体火箭发动机装药设计。e-mail: lixiaohuan111@126.com

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基金项目:

国家自然科学基金(U1404106); “十二五”总装预研项目(51328050101)


Low Temperature Accelerated Aging Study of Propellant Charge in Structural Tester
Author:
Affiliation:

(1. China Airborne Missile Academy, Luoyang 471009, China; 2. Air Force Military Representative Office in Baotou, Huhhot 010010, China; 3. The 46th Institute of the Sixth Academy of CASIC, Huhhot 010010, China)

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    摘要:

    采用低温加速老化试验的方法, 依据GJB770B-2005火药试验方法, 测试了6%、9%、12%和15%四种不同应变水平的结构试验器在单轴拉伸条件下的最大拉伸强度σm和最大伸长率εm, 考察了四种结构试验器中装药推进剂在低温(-28 ℃)下贮存性能随老化时间的变化趋势。结果表明:在低温应力应变情况下结构试验器中推进剂老化的主要原因是应力损伤。动态力学分析(DMA)试验(频率1 Hz, 振幅20 μm, 测试温度范围-100~80 ℃, 升温速率为3℃·min-1)证实推进剂确已发生损伤。常温拉伸(拉伸速度100 mm·min-1, 测试温度(23±2) ℃)情况下, 推进剂σm逐渐升高, 15%应变的结构试验器经过19周低温老化后, σm(0.96 MPa)与初始值(0.74 MPa)相比增加了近30%, εm基本在初始值附近波动; 低温快速拉伸(拉伸速度500 mm·min-1, 测试温度(-55±2) ℃情况下老化后期推进剂σm升高, εm明显下降, 15%应变的结构试验器经过19周低温老化后, σm(4.18 MPa)与初始值(3.77 MPa)相比增加了约11%, εm(26.8%)与初始值(37.6%)相比降低近29%。根据试验现象初步分析推进剂在低温应力情况下的老化机理可能是应力/应变作用下的物理损伤, 包括网络内聚损伤和固体颗粒与粘合剂界面“脱湿”。

    Abstract:

    In low temperature accelerated aging test method, using maximum tensile strength(σm) and maximum elongation(εm) under uniaxial stretching conditions as aging propellant characteristic parameters, the characteristic changing trend of propellant with different strain level in structural tester at -28 ℃ was studied. Results indicate that the main reason of the aging of propellant with strain is due to the stress damage under low temperature. The dynamic mechanical analysis (DMA)test validates that the damage of the propellant happenes. The σm of the propellant increases and the εm is waved with time gradually under normal temperature tension tests with the stretching speed of 100 mm·min-1, and the test temperature(23±2) ℃. And a fter 19 weeks low temperature aging, the σm of 15% strain structural tester was increased by nearly 30%. The σm of the propellant increases and εm was decreased greatly with time change under low temperature tension test with stretching rate of 500 mm·min-1and (-55±2) ℃. And after 19 weeks low temperature aging, the σm of 15% strain structural tester increases by nearly 11% and the εm decreases by nearly 29%. The ageing mechanism of propellant with strain under low temperature may be physical damage due to the effect of stress or strain, including net cohesion damage and the interface dewetting between solid grains and binder.

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引用本文

曹付齐,李小换,刘志成,等.结构试验器固体推进剂装药低温加速老化试验研究[J].含能材料, 2015, 23(7):648-652. DOI:10.11943/j. issn.1006-9941.2015.07.008.
CAO Fu-qi, LI Xiao-huan, LIU Zhi-cheng, et al. Low Temperature Accelerated Aging Study of Propellant Charge in Structural Tester[J]. Chinese Journal of Energetic Materials, 2015, 23(7):648-652. DOI:10.11943/j. issn.1006-9941.2015.07.008.

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  • 收稿日期: 2014-03-17
  • 最后修改日期: 2014-11-17
  • 录用日期: 2014-11-28
  • 在线发布日期: 2015-06-10
  • 出版日期: 2015-06-17