CHINESE JOURNAL OF ENERGETIC MATERIALS
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石蜡基凝胶燃料的制备及性能表征
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作者单位:

(南京理工大学机械工程学院, 江苏 南京 210094)

作者简介:

龚静芝(1991-),女,硕士生,主要从事凝胶推进剂制备及性能研究。e-mail: 1543688828@qq.com 通信联系人: 封锋(1982-),男,副教授,主要从事膏体(凝胶)推进技术研究。e-mail: nust203@aliyun.com

通讯作者:

封锋(1982-),男,副教授,主要从事膏体(凝胶)推进技术研究。e-mail: nust203@aliyun.com

基金项目:

航天科技创新基金(CASC03-02);中央高校基本科研业务费专项基金(30920140112001)


Preparation and Performance Characterization of Paraffin Based Gel Fuel
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(School of Mechanical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China)

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    摘要:

    以气相二氧化硅(A型)和改性蓖麻油(B型)为胶凝剂制备了两类石蜡凝胶,研究了胶凝剂类型对石蜡凝胶燃料体系稳定性、屈服应力、粘度和触变性的影响规律,采用HBE本构方程拟合了粘度曲线。结果表明,B型石蜡凝胶物理稳定性较好,受胶凝剂含量和离心力作用的影响较小; 石蜡凝胶屈服应力和粘度随胶凝剂含量的增加而增大,B型石蜡凝胶的屈服应力受胶凝剂含量的影响比A型小。石蜡凝胶的粘度随剪切速率的增大而减小,具有剪切稀化性,A型石蜡凝胶的幂律指数(n)值随胶凝剂含量的增加从-0.029变化到-0.172,B型石蜡凝胶的n值从0.510变化到0.342; A型和B型石蜡凝胶都有一定触变性,但其复凝性很弱。

    Abstract:

    Two types of paraffin gels were prepared by using the fumed silica(type A)and modified castor oil(type B)as gellants respectively. The influence of gel type on physical stability, yield stress, viscosity and thixotropy of differentgel types were investigated. The viscosity curves were fitted by using the Herschel-Bulkley(HBE) constitutive equation. Results show that there is little effect of gellant content and centrifugal force on the physical stability of type B paraffin gel, indicating that the physical stability of type B paraffin gel is better than type A paraffin gel. The yield stress and the viscosity of parffin gels increase with the increasing of the gellant content and the gellant content has less impact on the yield stress of type B than on type A. The viscosity of parffin gels decreases with the incrasing of the shear rate, and the parffin gels are shear thinning. The power-law index(n) of type A paraffin gel is from -0.029 to -0.172 with the increase of the gellant content and n for type B is from 0.510 to 0.342. The type A and type B paraffin gels all have a certain degree of thixotropy and little resilience.

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引用本文

龚静芝,封锋,邓寒玉,等.石蜡基凝胶燃料的制备及性能表征[J].含能材料, 2016, 24(6):560-564. DOI:10.11943/j. issn.1006-9941.2016.06.008.
GONG Jing-zhi, FENG Feng, DENG Han-yu, et al. Preparation and Performance Characterization of Paraffin Based Gel Fuel[J]. Chinese Journal of Energetic Materials, 2016, 24(6):560-564. DOI:10.11943/j. issn.1006-9941.2016.06.008.

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历史
  • 收稿日期: 2015-08-07
  • 最后修改日期: 2015-12-01
  • 录用日期: 2015-12-09
  • 在线发布日期: 2016-05-20
  • 出版日期: 2016-06-03