CHINESE JOURNAL OF ENERGETIC MATERIALS
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联氮杂芳环含能化合物研究进展
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作者单位:

(西安近代化学研究所, 陕西 西安 710065)

作者简介:

张俊林(1986-),男,工程师,主要从事含能材料合成与性能研究。e-mail: junlin-111@163.com 通信联系人: 王伯周(1967-),男,研究员,主要从事含能材料合成与性能研究。e-mail: wbz600@163.com

通讯作者:

王伯周(1967-),男,研究员,主要从事含能材料合成与性能研究。e-mail: wbz600@163.com

基金项目:

国家自然科学基金资助(201503162)


Review on the Aza-polyaromatic Ring Energetic Compounds
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Affiliation:

(Xi′an Modern Chemistry Research Institute, Xi′an 710065 )

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    摘要:

    联氮杂芳环化合物是一类重要的富氮含能化合物, 是国内外含能材料研究领域热点之一。氮杂芳环可通过N—N、C—N单键等不同键合方式而获得种类繁多的联氮杂芳环含能化合物, 主要包含对称型与非对称型两类结构, 也可按双环、三环及多环等环系特征进行分类。综述了呋咱、多氮唑等富氮环系通过N—N、C—N单键键合所形成的联氮杂芳环含能化合物研究进展, 重点评述了联氮杂芳环的构建方法及其含能化合物合成技术途径探索, 同时, 简要介绍了典型联氮杂芳环含能化合物的物化与爆轰性能。发展简捷、高效及条件温和的新型环系合成方法, 引入新型高能基团, 设计新型联氮杂芳环含能化合物应是今后该领域研究的重点。

    Abstract:

    Aza-polyaromatic ring energetic compounds are a kind of important nitrogen-rich energetic compounds, which are one of the hotspots in the research field of energetic materials at home and abroad. A wide variety of various aza-polyaromatic ring energetic compounds were obtained via different bonding methods of C—C or C—N single bond etc of aza-aromatic rings. These compounds mainly contain two kinds of symmetrical and nonsymmetrical structures. Their classification is also performed according to ring system characteristics of bicyclic, tricyclic and polycyclic structures. The synthesis of aza-polyaromatic ring compounds is simple. Currently, a large number of new high energy density compounds with excellent properties were obtained. In this paper, the research progresses on aza-polyaromatic ring energetic compounds consisted of furazans or azoles etc nitrogen-rich ring system, which are connected by C—C or C—N single bond, were summarized. The construction methodologies of aza-polyaromatic ring and the synthesis technology route of aza-polyaromatic ring energetic compounds are emphatically reviewed, at same time, the physicochemical and detonation performances of typical aza-polyaromatic ring energetic compounds were briefly introduced. Developing the synthesis method of new ring system with simple, efficient and mild reaction conditions, introducing new energetic groups and designing new aza-polyaromatic ring energetic compounds should be the emphasis of research in this field in the next stage.

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引用本文

张俊林,毕福强,王伯周,等.联氮杂芳环含能化合物研究进展[J].含能材料, 2016, 24(8):810-819. DOI:10.11943/j. issn.1006-9941.2016.08.015.
ZHANG Jun-lin, BI Fu-qiang, WANG Bo-zhou, et al. Review on the Aza-polyaromatic Ring Energetic Compounds[J]. Chinese Journal of Energetic Materials, 2016, 24(8):810-819. DOI:10.11943/j. issn.1006-9941.2016.08.015.

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历史
  • 收稿日期: 2015-12-24
  • 最后修改日期: 2016-02-19
  • 录用日期: 2016-03-11
  • 在线发布日期: 2016-08-08
  • 出版日期: 2016-09-01