CHINESE JOURNAL OF ENERGETIC MATERIALS
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基于分段老化模型的HTPB推进剂贮存寿命
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(军械工程学院, 河北 石家庄 050003)

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杜永强(1991-),男,硕士研究生,主要从事复合固体推进剂老化性能及建模研究。e-mail: dyqangus@163.com

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Storage Life of HTPB Propellant Based on Segmented Aging Model
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(Ordnance Engineering College, Shijiazhuang 050003, China)

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    摘要:

    针对常用老化模型不能准确描述端羟基聚丁二烯(HTPB)推进剂贮存老化不同阶段特点的问题,提出了一种分段老化模型。对HTPB推进剂进行了高温加速寿命试验,以最大延伸率作为性能变化表征参数,将HTPB推进剂的老化机理分三个阶段进行了分析,并根据老化不同阶段的相关性分析结果,建立了分段老化模型。利用时温等效原理,得到了高温(60 ℃)加速老化和常温(25 ℃)有效贮存的时间转换关系,结合分段老化模型,预估HTPB推进剂在常温(25 ℃)条件下贮存寿命为11.60年。该模型的相关系数R>0.95, 标准差Rstd<0.015。

    Abstract:

    To solve the problem that the Hydroxyl-Terminated Polybutadiene(HTPB) propellant aging characteristics at different storage stages cannot be described by commonly used aging models accurately, the segmented aging model was proposed. The high temperature accelerated life test of the HTPB propellant was carried out, and the aging mechanism of HTPB propellant was analyzed in three stages by using the maximum elongation as the characteristic parameter. According to the correlation analysis results of different aging stages, the segmented aging model was established. The time conversion relationship between high temperature (60 ℃) accelerated aging and room temperature (25 ℃) effective storage was obtained by using the time-temperature equivalence principle, and the storage life of HTPB propellant at room temperature (25 ℃) is predicted for 11.60 years by combing with the segmented aging model. The correlation coefficient R of the segmented aging model is more than 0.95, and the standard deviation Rstd is less than 0.015.

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引用本文

杜永强,郑坚,彭威,等.基于分段老化模型的HTPB推进剂贮存寿命[J].含能材料, 2016, 24(10):936-940. DOI:10.11943/j. issn.1006-9941.2016.10.002.
DU Yong-qiang, ZHENG Jian, PENG Wei, et al. Storage Life of HTPB Propellant Based on Segmented Aging Model[J]. Chinese Journal of Energetic Materials, 2016, 24(10):936-940. DOI:10.11943/j. issn.1006-9941.2016.10.002.

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历史
  • 收稿日期: 2016-03-18
  • 最后修改日期: 2016-05-18
  • 录用日期: 2016-05-18
  • 在线发布日期: 2016-10-08
  • 出版日期: 2016-10-14