CHINESE JOURNAL OF ENERGETIC MATERIALS
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NG/NC吸收药片的溶胀行为
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(西安近代化学研究所, 陕西 西安 710065)

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王琼(1985-),男,工程师,主要从事火炸药装药环境适应性与寿命评估研究。e-mail: 0304140125@163.com

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Swelling Behaviors of NC/NG Absorbent Tablets
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(Xi′an Modern Chemistry Research Institute, Xi′an 710065, China)

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    摘要:

    为探索硝化棉(NC)/硝化甘油(NG)吸收药片的最佳溶胀溶剂以及吸收药片预烘处理对溶胀行为的影响, 采用称重法研究了经过预烘处理和未经预烘处理的吸收药片在乙酸乙酯和丙酮单一溶剂以及乙醚/乙醇、乙醇/丙酮和乙醇/乙酸乙酯等混合溶剂中的自由溶胀过程, 并采用“示线追踪法”研究了丙酮, 乙酸乙酯和乙醇/乙醚混合溶剂(V乙醇:V乙醚=1:2) 在吸收药条中的一维扩散行为。获得了吸收药片在各溶剂中的自由溶胀动力学方程以及丙酮、乙酸乙酯和乙醇/乙醚(V乙醇:V乙醚=1:2) 三种溶剂在吸收药条中的一维扩散方程。结果表明, 从溶胀速率和平衡溶胀度综合考虑, 乙酸乙酯和乙醇/乙酸乙酯对吸收药片的综合溶胀效果最优; 预烘处理能提高吸收药片在溶剂中平衡溶胀度以及初始溶胀速率; 吸收药片在溶剂中的溶胀速率与溶剂在吸收药片中的“一维扩散”速率无直接相关性。

    Abstract:

    To explore the best solvent of swelling the nitrocellulose(NC)/nitroglycerin(NG) absorbent tablets and the influence of predrying treatment on the swelling behaviors of absorbent tablet, the free swelling process of absorbent tablet with or without predrying treatment in single solvent such as acetone and ethyl acetate and mixed solvents such as ether/ethanol, ethanol/acetone and ethanol/ethyl acetate et aletc., was studied using the weighting method. One dimension diffusion behaviors of solvents, acetone, ethyl acetate and ethanol/ether (Vethanol:Vether=1:2) in absorbent bar were studied by "line tracing method". The free swelling kinetic equations of the absorbent tablets in various solvents and one dimension diffusion equations of three solvents, acetone, ethyl acetate and ethanol/ether (Vethanol:Vether=1:2) in absorbent bar were obtained. Results show that from the comprehensive consideration of swelling rate and equilibrium swelling degree, the comprehensive swelling effect of ethyl acetate and ethanol/ethyl acetate are the best for absorbent tablets. The predrying treatment can improve the equilibrium swelling degree and initial swelling rate of absorbent tablets in the solvents. There is no direct correlation between the swelling rate of absorbent tablet in the solvents and "one dimension diffusion" rate of solvents in absorbent tablets.

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引用本文

王琼,邓重清,蔚红建,等. NG/NC吸收药片的溶胀行为[J].含能材料, 2017, 25(7):591-596. DOI:10.11943/j. issn.1006-9941.2017.07.010.
WANG Qiong, DENG Chong-qing, WEI Hong-jian, et al. Swelling Behaviors of NC/NG Absorbent Tablets[J]. Chinese Journal of Energetic Materials, 2017, 25(7):591-596. DOI:10.11943/j. issn.1006-9941.2017.07.010.

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历史
  • 收稿日期: 2016-08-22
  • 最后修改日期: 2017-02-13
  • 录用日期: 2017-02-16
  • 在线发布日期: 2017-07-14
  • 出版日期: 2017-07-21