The syntheses and performances of some new insensitive individual explosives are introduced,including nitro-compound explosives FOX-7,LLM-105,MTNI, 4,6-nityoanilinodinitrobenzofuroxans,PL-1,LLM-116,ANTZ,nitramine explosives I-RDX,TEX and other explosives DAAT,DAAF,DAAzF. The detailed synthetic procedures and a few PBX′s formulations based on the insensitive explosives mentioned above are given,especially those for FOX-7 and LLM-105. In addition,some reference data concerning the properties of a number of insensitive explosives are summarized in this paper. FOX-7 and LLM-105 are attractive for applications in insensitive munitions due to their high energy level,moderate sensitivity,and good thermal stability.