CHINESE JOURNAL OF ENERGETIC MATERIALS
+Advanced Search

Synthesis of High-Nitrogen Compound of 4,4′,6,6′-Tetra(azido)azo-1,3,5-triazine
Author:
Affiliation:

Fund Project:

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
    Abstract:

    4,4′,6,6′-Tetra(azido)azo-1,3,5-triazine(TAAT) was synthesized with cyanuric chloride and hydrazine hydrate as primary materials. This synthesis is a four-step process including coupling,hydrazinolysis,diazotization and oxidation in turn. Each reaction process,especially the oxidizing reaction is described in details. The investigation indicates that chlorine can transform 94% 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine into TAAT but N-bromosuccinimide just transforms 84%. The DSC,IR,NMR and elemental analysis determine the structure of TAAT and its intermediates. The characterization of DSC shows TAAT decomposes at 198 ℃. A free radical mechanism is presented to interpret the oxidizing reaction.

    Reference
    Related
    Cited by
Article Metrics
  • PDF:
  • HTML:
  • Abstract:
  • Cited by:
Get Citation

李小童,庞思平,于永忠,等.高氮化合物4,4′,6,6′-四叠氮基偶氮-1,3,5-三嗪的合成研究[J].含能材料,2007,15(5):485-489.
LI Xiao-tong, PANG Si-ping, YU Yong-zhong, et al. Synthesis of High-Nitrogen Compound of 4,4′,6,6′-Tetra(azido)azo-1,3,5-triazine[J]. Chinese Journal of Energetic Materials,2007,15(5):485-489.

Cope
History
  • Received:October 10,2006
  • Revised:
  • Adopted:
  • Online: November 01,2011
  • Published: