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Research on Rheological Properties and Curing Kinetics of B-GAP-based Propellant Slurry
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1.School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China;2.Shanxi Engineering Technology Research Center for Ultrafine Powder, Taiyuan 030051, China;3.Xi′an Modern Chemistry Research Institute, Xi′an 710065, China

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    Abstract:

    To study the rheological properties and to cure the reaction process of branched polyglycidyl azide (B-GAP)-based propellent, the slurries were tested by rheological research methods, and the changes of viscosity with shear rate and modulus with time at 50, 55, 60 ℃ and 65 ℃ were studied. The results indicate: B-GAP propellant slurry has a shear thinning properties and belongs to pseudoplastic non-Newtonian fluid; The curing reaction rate of the propellant slurry increases as the curing reaction progresses, reaching a maximum value when the curing degree is 0.3, and then the reaction rate begins to decrease until zero; Temperature has a great influence on the kinetics of propellant curing reaction. Within a certain temperature range, the peak value of the curing reaction rate increases with the increase of temperature, and the maximum value of storage modulus decreases with the increase of temperature; Based on the power law equation and Arrhenius equation, the constitutive equation and curing kinetic reaction equation of B-GAP slurry was obtained.

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卢鑫浩,叶宝云,程王健,等. B-GAP基推进剂药浆流变特性和固化动力学研究[J].含能材料,2022,30(11):1083-1089.
LU Xin-hao, YE Bao-yun, CHENG Wang-jian, et al. Research on Rheological Properties and Curing Kinetics of B-GAP-based Propellant Slurry[J]. Chinese Journal of Energetic Materials,2022,30(11):1083-1089.

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History
  • Received:December 06,2021
  • Revised:September 29,2022
  • Adopted:May 23,2022
  • Online: September 29,2022
  • Published: November 25,2022