CHINESE JOURNAL OF ENERGETIC MATERIALS
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Research Progress of Energetic Compounds based on 1,2,3-Triazole Frameworks
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1.School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China;2.Beijing Institute of Aerospace Testing Technology,Beijing Key Laboratory of Research and Application for Arospace Green Propellants, Beijing 100074,China

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    Abstract:

    This review focused on the four major construction methods of 1,2,3-triazole energetic materials and corresponding research progress since the 1960s, including: Ⅰ) energetic compounds constructed based on 1-amino-1,2,3-triazole; Ⅱ) energetic compounds constructed based on dicyano substituted 1,2,3-triazole; Ⅲ) 1,2,3-triazole based energetic compounds prepared through azide involved cyclization reaction; Ⅳ) fused polycyclic energetic compounds built from 1,2,3-triazole. By analyzing the relationship between the molecular structure and energetic properties of several representative 1,2,3-triazole based energetic compounds, the influence of molecular structures on their energetic performances and stabilities could be profoundly clarified. Meanwhile, the potential application values of the mentioned high-performance 1,2,3-triazole based energetic compounds, such as their application prospects of main explosives, heat-resistant explosives and lead-free primary explosive, were discussed, providing a reference for the design and development of next-generation high energy density materials (HEDMs).

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蔺向阳,曹宇鹏,张西亚.基于1,2,3-三唑骨架的含能化合物研究进展[J].含能材料,2023,31(1):92-106.
LIN Xiang-yang, CAO Yu-peng, ZHANG Xi-ya. Research Progress of Energetic Compounds based on 1,2,3-Triazole Frameworks[J]. Chinese Journal of Energetic Materials,2023,31(1):92-106.

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History
  • Received:January 09,2022
  • Revised:October 28,2022
  • Adopted:May 18,2022
  • Online: October 25,2022
  • Published: January 25,2023