CHINESE JOURNAL OF ENERGETIC MATERIALS
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发射药喷涂涂覆中涂覆液溶剂比的选择
作者:
作者单位:

(江苏省南京理工大学化工学院装药技术研究所, 江苏 南京 210094)

作者简介:

孙鹏飞(1989-),男,博士研究生,主要从事发射药性能研究。e-mail: superb_spf@hotmail.com 通信联系人: 廖昕(1961-),男,研究员,主要从事发射药配方及性能研究。e-mail: liaoxin331@163.com

通讯作者:

廖昕(1961-),男,研究员,主要从事发射药配方及性能研究。e-mail: liaoxin331@163.com

基金项目:

国家自然科学基金资助(51506093)


Selection of Solvent Ratios for Coating Solution in Gun Propellants Spraying Coating
Author:
Affiliation:

(School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China)

Fund Project:

The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    为了优化端面局部阻燃发射药(端面涂覆, 且小孔保持通气状态)涂覆层制备的喷涂工艺中涂覆液溶剂比, 采用醋酸丁酸纤维素(CAB)作钝感剂, CAB与吸收药片TG-1(皮罗棉和硝化甘油为主要组分)作溶质, 乙醇-丙酮(V/V=1/1) 为溶剂, 按照不同溶剂比制备得到涂覆液, 用此涂覆液采用喷涂的工艺制成了涂覆层薄膜和涂覆发射药, 利用万能材料测试仪获得涂覆层薄膜的力学强度, 并利用三维视频对涂覆层在拉伸前、后的表面结构进行了局部放大观察分析, 对不同溶剂比的涂覆发射药进行了密闭爆发器试验。结果表明, 涂覆层的力学强度、表面及断裂处形貌与溶剂比有明显联系, 溶剂比主要影响了涂覆层材质的均匀性和致密性, 是影响涂覆层力学强度的重要因素, 从而对涂覆发射药的燃烧渐增性产生影响。当溶剂比为8:1时, 露孔率达到95%以上, 同时获得的涂覆层表面最为光滑, 其薄膜的拉伸强度最大, 为49.75 MPa, 断裂处最为整齐, 涂覆发射药的燃气动态活度变化值达到0.0920 MPa-1·s-1, 为所有样品中的最大值。

    Abstract:

    To optimize the solvent ratio of the coating solution in spraying process of preparing the coating layer of gun propellant with local end-coating flame retardant, the coating solution was prepared using cellulose acetate butyrate (CAB) as desensitized agent, mixture composed of CAB and absorption propellant tablets TG-1 with main components of nitrocellulose and nitroglycerin as solute, ethanol/ acetone of V/V=1/1 as solvent, according to different solvent ratios. Applying the coating solution, the films of coating layers and coated propellants were produced by spraying coating technology. The mechanical strength of the films of coating layers was obtained by an universal material tester. The local amplification observation and analysis of 3D video for surface structure of coating layers before and after tension were performed.The coated propellants were tested by the closed bomb experiments. Results show that the mechanical strength and morphology of both surface and fracture of coating layers are significantly related to solvent ratios. The solvent ratios affect the uniformity and compactness of coating layer materials mainly and are important factor affecting the mechanical strength of coating layers. Thereby, the combustion progressivity of coated propellants is effected.When the solvent ratio is 8:1, the porosity rate is over 95%. At the meantime, the surface of the coating layer obtained is the best smooth, the tensile strength of its film is the maximum, its value is 49.75 MPa, the fracture is the most tidy and the change value in combustion gas dynamic activity for coated propellant achieves a maximum value of 0.0920 MPa-1·s-1 in all samples.

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引用本文

孙鹏飞,廖昕,王泽山.发射药喷涂涂覆中涂覆液溶剂比的选择[J].含能材料, 2017, 25(9):712-716. DOI:10.11943/j. issn.1006-9941.2017.09.002.
SUN Peng-fei, LIAO Xin, WANG Ze-shan. Selection of Solvent Ratios for Coating Solution in Gun Propellants Spraying Coating[J]. Chinese Journal of Energetic Materials, 2017, 25(9):712-716. DOI:10.11943/j. issn.1006-9941.2017.09.002.

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  • 收稿日期: 2017-03-28
  • 最后修改日期: 2017-06-07
  • 录用日期: 2017-06-08
  • 在线发布日期: 2017-09-22
  • 出版日期: 2017-09-29