CHINESE JOURNAL OF ENERGETIC MATERIALS
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叠氮硝化甘油的合成研究
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郭绍俊(1942-),男,研究员,长期从事含能材料合成与应用研究。

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国防科技预研基金资助(J12.6.2)


Synthesis of 1,3-diazido-2-nitryloxypropane
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    摘要:

    以1,3-二氯丙醇-(2)为原料成功地合成了硝化甘油二叠氮取代物——1,3-二叠氮基-2-硝酸酯基丙烷(DANG),并对DANG性能进行了初步测试。试验结果表明,DANG的凝固点明显低于NG的凝固点,而危险等级与硝甘相当或略低。

    Abstract:

    1,3-diazido-2-nitryloxypropane(DANG),also know as azido-substituted nitrglycerin (NG),was synthesized using 1,3-dichloro-2-propanol as starting material via azidation and nitration. The structures of both DANG and its intermediate 1,3-diazido-2-propanol (DAHP) were identified by IR,1HNMR and elemental analysis. HPLC results show that the purity is 98.0% for DAHP and 96.0% for DANG respectively. In addition,some important properties of DANG,including solidafication point,thermal stability,friction sensitivity,and impact sensitivity were all determined,and it has been proved that DANG remains liquid state at -15 ℃.

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郭绍俊,苏天铎,封利民,等.叠氮硝化甘油的合成研究[J].含能材料, 2003, 11(3):149-152.
GUO Shao-jun, SU Tian-duo, FENG Li-min, et al. Synthesis of 1,3-diazido-2-nitryloxypropane[J]. Chinese Journal of Energetic Materials, 2003, 11(3):149-152.

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  • 收稿日期: 2002-10-08
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  • 在线发布日期: 2011-11-02
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