CHINESE JOURNAL OF ENERGETIC MATERIALS
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聚氨酯原位结晶包覆HMX的研究
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曾贵玉(1969-),男,博士,主要从事含能材料配方研制及含能材料微纳化技术与性能研究。e-mail: guiyuzeng@126.com

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中国工程物理研究院重大基金(2009A0302017)


In-situ Crystallization Coating HMX by Polyurethane
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    摘要:

    为有效降低HMX的机械感度,采用聚氨酯与HMX原位结晶的方法对HMX进行包覆改性处理。借助扫描电镜(SEM)、激光粒度仪、X-射线衍射、机械感度测试等方法表征改性前后HMX的粒子形态、粒径、晶型、撞击感度和摩擦感度。结果表明,原位结晶包覆处理后的HMX晶体质量得到明显改善,晶体形貌更规整、颗粒表面缺陷显著减少,β-晶型没有改变,改性处理后HMX的撞击感度和摩擦感度分别从90%和70%降低到12%和36%。原位结晶包覆法是一种能有效降低炸药机械感度的方法。

    Abstract:

    In order to reduce the mechanical sensitivity of HMX efficiently, polyurethane in-situ crystallization coating method was used to modify HMX. The particle morphology, particle size, crystal type, impact sensitivity and friction sensitivity of original HMX and modified HMX were characterized by scan electric microscopy(SEM), laser light scattering sizer, X-ray diffraction(XRD) and mechanical sensitivity test.The results show that the crystal quality of modified HMX has been improved significantly, crystal shape is more orbicular and particle surface has less defects compared with the original HMX sample. The crystal type of modified HMX is β which is the same as that of original HMX. The impact sensitivity and friction sensitivity of modified HMX reduce from 90% and 70% of original HMX to 12% and 36% respectively which indicates in-situ crystallization coating method is an efficient means of decreasing the mechanical sensitivity of HMX.

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曾贵玉,聂福德,刘兰,等.聚氨酯原位结晶包覆HMX的研究[J].含能材料, 2011, 19(2):138-141. DOI:10.3969/j. issn.1006-9941.2011.02.004.
ZENG Gui-yu, NIE Fu-de, LIU Lan, et al. In-situ Crystallization Coating HMX by Polyurethane[J]. Chinese Journal of Energetic Materials, 2011, 19(2):138-141. DOI:10.3969/j. issn.1006-9941.2011.02.004.

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  • 收稿日期: 2010-06-28
  • 最后修改日期: 2010-11-09
  • 录用日期: 2010-10-12
  • 在线发布日期: 2012-02-22
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