CHINESE JOURNAL OF ENERGETIC MATERIALS
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TNAZ/ANTA最低共熔物的制备与性能
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《中国科学》杂志社,中国工程物理研究院化工材料研究所 绵阳,中国工程物理研究院化工材料研究所 绵阳,中国工程物理研究院化工材料研究所 绵阳,中国工程物理研究院化工材料研究所 绵阳,中国工程物理研究院化工材料研究所 绵阳,北京理工大学化工与环境学院

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张学梅(1979-),女,博士,主要从事高能低感炸药的合成及混合炸药配方设计。e-mail: zh_xuemei@126.com

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Preparation and Properties of Lowest Eutectic Mixture TNAZ/ ANTA
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Science China Press,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,School of Chemical Engineering Environment,Beijing Institute of Technology

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    摘要:

    为寻求可替代梯恩梯用于熔铸炸药的液相载体,研究绘制了1,3,3-三硝基氮杂环丁烷(TNAZ)与3-氨基-2,4,6-三硝基苯甲醚(ANTA)混合物的二元相图,并测定了最低共熔物的感度、热安定性、爆轰性能。结果表明,当TNAZ与ANTA质量比为60/40时为最低共熔物,共熔点为84 ℃; 最低共熔物热分解温度高、热安定性好、撞击感度、摩擦感度和静电火花感度与TNT相当,做功能力相当于148% TNT和114% Comp.B; 70 ℃恒温放置6 h不渗油,是一种具有潜力的可替代TNT的熔铸炸药。 

    Abstract:

    A phase diagram of 1,3,3-trinitroazetidine(TNAZ) and 3-amino-2,4,6-trinitroanisole (ANTA) was draw by origin software and the sensitivity, thermal stability, and detonation performance of the eutectic mixture were tested in order to design a potential TNT replacement for melt-cast explosive. The results show that when the weight percent of 3-methoxy-2,4,6-trinitrobenzenamine is 40%, the mixture has the lowest melting point, 84 ℃. The eutectic mixture has good thermal stability and its friction sensitivity, impact sensitivity, electrostatics sensitivity are comparable to TNT. The working capability of the mixture is 148% equivalent to TNT and 114% equivalent to Comp.B. Furthermore, another advantage of eutectic mixture is that there is no permeability oil at 70 ℃ for 6 h. These results indicate that the eutectic mixture is a potential replacement of TNT for melt-cast explosive. 

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张学梅,董海山,孙杰,等. TNAZ/ANTA最低共熔物的制备与性能[J].含能材料, 2012, 20(5):555-559. DOI:10.3969/j. issn.1006-9941.2012.05.008.
ZHANG Xue-mei, DONG Hai-shan, SUN Jie, et al. Preparation and Properties of Lowest Eutectic Mixture TNAZ/ ANTA[J]. Chinese Journal of Energetic Materials, 2012, 20(5):555-559. DOI:10.3969/j. issn.1006-9941.2012.05.008.

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  • 收稿日期: 2012-08-17
  • 最后修改日期: 2012-08-27
  • 录用日期: 2012-09-04
  • 在线发布日期: 2012-09-26
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