CHINESE JOURNAL OF ENERGETIC MATERIALS
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新型HMX/AP/EP纳米复合物的制备及表征(英)
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(四川省西南科技大学非金属复合与功能材料重点实验室, 四川 绵阳 621010)

作者简介:

Liao Ning(1988-),male,master, research fields: preparation of nano-energy materials. e-mail: lynn195200@163.com

通讯作者:

Liao Ning(1988-),male,master, research fields: preparation of nano-energy materials. e-mail: lynn195200@163.com Corresponding Author: Duan Xiao-hui(1970-), female, Professor, research fields: preparation of co-crystal explosive and simulation. e-mail: duanxiaohui@swust.edu.cn

基金项目:

The Key Research Project of Sichuan Province (No.10zd1106) and Postgraduate Innovation Fund Project by Southwest University of Science and Technology(No.14ycx014) Biography: Liao Ning(1988-),male,master, research fields: preparation of nano-energy materials. e-mail: lynn195200@163.com


Preparation and Characterization of a Novel HMX/AP/EP Nanocomposite
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(State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials Key Laboratory Southwest University of Science and Technology, Mianyang 621010, China)

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    摘要:

    以含能聚合物(EP)为基底通过共沉淀法制备了奥克托今(HMX)/高氯酸铵(AP)/含能聚合物(EP)纳米复合物。用扫描电镜(SEM), 能量色散X射线能谱(EDS)、比表面积(Brunauer-Emmett-Teller(BET))测定、红外(IR)光谱法和差示扫描量热法(DSC)表征了它的结构及性能。结果表明,HMX/AP/EP纳米复合物具有三维纳米网状结构。HMX和AP均匀沉积在EP上面,其尺寸为50~200 nm。HMX、AP和EP紧密结合在一起,具有良好的相容性。HMX/AP/EP纳米复合物的分解温度远低于HMX的。当HMX/AP/EP纳米复合物的氧平衡为零时,其分解热高达2570 J·g-1。HMX/AP/EP纳米复合物的撞击特性落高H50为50.49 cm,与HMX的撞击感度的特性落高(27 cm)相比,其机械感度较低。

    Abstract:

    The cyclotetramethylene tetranitramine (HMX)/ammonium perchlorate (AP)/energetic polymer (EP) nanocomposite was prepared by a co-precipitation method using a novel EP as matrix. Its structure and properties were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), specific surface area (Brunauer-Emmett-Teller (BET)) measurement, Infrared (IR) spectrometry, and differential scanning calorimetry (DSC). Results show that the HMX/AP/EP nanocomposite possesses the three-dimensional nano-network structure. The HMX and AP particles are uniformly deposited on EP, whose size is in the range of 50-200 nm. HMX, AP and EP are closely bonded each other with good compatibility. The thermal decomposition temperature of the HMX/AP/EP nanocomposite is far lower than that of HMX. When the oxygen balance of HMX/AP/EP nanocomposite is zero, its decomposition heat is up to 2570 J·g-1.Compared with the characteristic drop height of impact sensitivity (H50) of 27 cm of HMX, the value of H50 of the HMX/AP/EP nanocomposite is 50.49 cm, revealing that the latter has lower mechanical sensitivity.

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引用本文

廖宁,李兆乾,李文鹏,等.新型HMX/AP/EP纳米复合物的制备及表征(英)[J].含能材料, 2015, 23(7):709-711. DOI:10.11943/j. issn.1006-9941.2015.07.018.
LIAO Ning, LI Zhao-qian, LI Wen-peng, et al. Preparation and Characterization of a Novel HMX/AP/EP Nanocomposite[J]. Chinese Journal of Energetic Materials, 2015, 23(7):709-711. DOI:10.11943/j. issn.1006-9941.2015.07.018.

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历史
  • 收稿日期: 2014-10-12
  • 最后修改日期: 2014-12-26
  • 录用日期: 2015-01-05
  • 在线发布日期: 2015-06-10
  • 出版日期: 2015-06-17