CHINESE JOURNAL OF ENERGETIC MATERIALS
+高级检索
石蜡/Estane5703复合钝感包覆CL-20的研究
作者:
作者单位:

(北京理工大学机电学院, 北京 100081)

作者简介:

魏华(1990-),男,硕士研究生,主要从事高能钝感混合炸药研究。e-mail: wei_bit1991@163.com 通信联系人: 焦清介(1958-),男,教授,主要从事高能钝感混合炸药研究。e-mail: jqj@bit.edu.cn

通讯作者:

焦清介(1958-),男,教授,主要从事高能钝感混合炸药研究。e-mail: jqj@bit.edu.cn

基金项目:

国家自然科学基金资助(11172042)


Desensitizing Technology of CL-20 by Coating Wax and Estane5703
Author:
Affiliation:

(School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China)

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
    摘要:

    为降低六硝基六氮杂异伍兹烷 (CL-20) 的机械感度, 采用水悬浮法, 以钝感剂石蜡及高分子聚合物Estane5703为包覆原料包覆CL-20, 制备了4种包覆颗粒。用X射线衍射仪 (XRD)、扫描电镜 (SEM)、差示扫描量热分析 (DSC)、机械感度测试方法表征包覆前后CL-20的晶型、包覆状态、热分解温度、机械感度。结果表明, 石蜡与Estane5703可完整包覆CL-20, 且包覆后CL-20的ε晶型未发生改变。采用水悬浮法包覆CL-20, 当石蜡/Estane5703含量为总体系质量的2%/2%时, CL-20的撞击感度由100%降低至40%, 摩擦感度由100%降低至48%;放热峰温提高5.4 ℃。

    Abstract:

    Four kinds of hexanitrohexaazaisowurtzitane (CL-20) based composite particles were prepared by slurry method using CL-20 as filler, wax and Estane5703 as desensitizers. The crystal form, state of coatiing, thermal decomposition temperature of samples before and after coating were characterized by X-ray diffractometer (XRD), scanning electron microscope (SEM), differential scanning calorimeter (DSC), and the mechanical sensitivity was tested. Results show that CL-20 is coated by wax and Estane5703 perfectly, and the ε crystal form of CL-20 was not changed. The impact sensitivity and friction sensitivity of CL-20 decrease from 100% to 40% and 48%, and thermal decomposition peak temperature increases by 5.4 ℃ compared with raw material when the wax and Estane5703 content are all 2%.

    参考文献
    相似文献
    引证文献
文章指标
  • PDF下载次数:
  • HTML阅读次数:
  • 摘要点击次数:
  • 引用次数:
引用本文

魏华,焦清介,郭学永.石蜡/Estane5703复合钝感包覆CL-20的研究[J].含能材料, 2017, 25(4):321-325. DOI:10.11943/j. issn.1006-9941.2017.04.009.
WEI Hua, JIAO Qing-jie, GUO Xue-yong. Desensitizing Technology of CL-20 by Coating Wax and Estane5703[J]. Chinese Journal of Energetic Materials, 2017, 25(4):321-325. DOI:10.11943/j. issn.1006-9941.2017.04.009.

复制
历史
  • 收稿日期: 2016-09-09
  • 最后修改日期: 2016-12-21
  • 录用日期: 2017-01-18
  • 在线发布日期: 2017-04-26
  • 出版日期: 2017-04-27