CHINESE JOURNAL OF ENERGETIC MATERIALS
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Effect of FOX-7 on Combustion Performance of NC/TMETN Based Low-sensitive and Smokeless CMDB Propellant
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1.Xi’an Modern Chemistry Research Institute, Xi’an 710065, China;2.Beijing Institute of LongMarch Vehicle, Beijing 100076, China

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    Abstract:

    The effects of mass fraction and particle size of 1,1-diamino-2,2-dinitroethylene(FOX-7),different composite combustion catalysts with lead, copper and carbon on the combustion performance of nitrocellulose (NC)/trimethylotethane reinitiate(TMETN) low-insensitive and smokeless composite modified double base(CMDB) propellant with screw extrusion process were investigated by means of strand burner method. The results shown that the burning rate of CMDB propellant is first rise and then descend with the addition of FOX-7. When the FOX-7 content is 25%,the burning rate of CMDB propellant rised from 5.87 mm·s-1 to 14.90 mm·s-1 at 10 MPa, and when the content of FOX-7 increases from 25% to 30%, the burning rate decreased from 14.90 mm·s-1 to 12.78 mm·s-1 at 10 MPa. The pressure exponent of burning rate between 6-16 MPa decrease from 0.97 to 0.60 as the mass fraction of FOX-7 in the formulation increased from 5 % to 30 %. When the FOX-7 be replaced by finer particles FOX-7 with the same mass, the burning rate decreased 1.16 mm·s-1 at 10 MPa, while the pressure exponent of burning rate between 6-14 MPa increased. The burning rate of propellant with addition of β-Pb/β-Cu/CB combustion catalyst increases from 14.90 mm·s-1 to 18.65 mm·s-1 at 10 MPa, while the pressure exponent of burning rate between 6-16 MPa decrease from 0.63 to 0.35, which compared with the referenced formulation (no combustion catalyst).

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张超,王寅虎,杨立波,等. FOX-7对NC/TMETN基低敏感无烟改性双基推进剂燃烧性能的影响[J].含能材料,2020,28(3):229-234.
ZHANG Chao, WANG Yin-hu, YANG Li-bo, et al. Effect of FOX-7 on Combustion Performance of NC/TMETN Based Low-sensitive and Smokeless CMDB Propellant[J]. Chinese Journal of Energetic Materials,2020,28(3):229-234.

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History
  • Received:May 05,2019
  • Revised:October 08,2019
  • Adopted:July 08,2019
  • Online: October 08,2019
  • Published: March 25,2020