CHINESE JOURNAL OF ENERGETIC MATERIALS
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Energy Output Behaviors of Suspended AlH3 Dust in Explosive Venting
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1.School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China;2.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;3.Science and Technology on Combustion and Explosion Laboratory, Xi′an Modern Chemistry Research Institute, Xi′an 710065, China

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    Abstract:

    To study the energy output law of the suspended AlH3 dust in explosion and release process, a modified 20 L ball explosion test system was used to study the explosion pressure and flame propagation law in closed and venting conditions alternately. The results showed that the lower explosion limit concentration of suspended AlH3 in a closed system decreased from 40 g·m-3 to 30 g·m-3 comparing with aluminum powder, indicating that the hydrogen released by the burning AlH3 accelerated the entire chemical reaction process. In addition, both the maximum explosion pressure and explosion pressure rise rate of AlH3 dust explosion in a closed system were higher than that of the aluminum powder. The maximum explosion pressure rose from 1.02 MPa to 1.15 MPa, indicating that a combustible gas-dust composite system was formed due to the release of hydrogen to exacerbate the violence of the explosion energy release process. Under venting conditions, when the concentration of AlH3 dust was 500 g·m-3, the explosion pressure (p) and pressure rise rate (dp/dt) decreased the most, reaching 43% and 30% respectively, indicating explosion venting can effectively reduce explosion damage. Moreover, it was concluded that the length and speed of the explosion vent flame reached the peak values when the concentration of AlH3 was 750 g·m-3, meanwhile the probability and frequency of multiple flames presented a positive correlation with the concentration.

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曹卫国,赵懿明,吴星亮,等.悬浮态AlH3粉尘爆炸泄放过程能量输出规律[J].含能材料,2021,29(10):985-992.
CAO Wei-guo, ZHAO Yi-ming, WU Xing-liang, et al. Energy Output Behaviors of Suspended AlH3 Dust in Explosive Venting[J]. Chinese Journal of Energetic Materials,2021,29(10):985-992.

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History
  • Received:June 30,2021
  • Revised:August 20,2021
  • Adopted:July 20,2021
  • Online: August 16,2021
  • Published: October 25,2021