CHINESE JOURNAL OF ENERGETIC MATERIALS
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含超细铝粉AP/HTPB复合固体推进剂的燃烧特性研究
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南京理工大学

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Combustion Characterization of Composite Solid Propellants Containing Ultrafine Aluminum AP/HTPB
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Nanjing University of Science and Technology

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    摘要:

    固体火箭推进剂的燃烧性能优化对发动机性能提升具有重要意义,其中铝颗粒因其高反应活性和高能量密度被广泛用作金属添加剂。基于气相五步反应机理构建了AP/HTPB/AL二维周期性三明治均质化稳态燃烧模型,并通过数值模拟与实验数据对比验证了模型的可靠性。研究发现,随着压力从0.2 MPa增至6.5 MPa,火焰结构呈现从预混燃烧向扩散燃烧转变的演化规律,同时热释放核心逐渐向燃烧表面靠近。在恒定压力条件下,推进剂的燃烧速率随超细铝粉(UFAL)含量的增加显著提高。然而,不同UFAL含量的推进剂在压力敏感性方面表现出明显差异,显示出在实现高燃速与维持燃速稳定性之间存在一定的平衡区间。

    Abstract:

    Combustion performance optimization of solid rocket propellants critically enhances engine efficiency. Aluminum (Al) particles serve as prevalent metallic additives due to their high reactivity and energy density. A two-dimensional periodic sandwich homogenized steady-state combustion model was developed for AP/HTPB/Al propellants based on a five-step gas-phase reaction mechanism. Numerical simulations validated model reliability against experimental data. Increasing pressure from 0.2 MPa to 6.5 MPa transitions flame structures from premixed to diffusion combustion. Simultaneously, heat-release cores shift closer to the burning surface. At constant pressure, propellant burning rates rise significantly with higher ultra-fine aluminum (UFAL) content. UFAL concentration variations, however, produce distinct pressure sensitivity differences. This indicates a trade-off interval exists between achieving high burning rates and maintaining rate stability. These findings advance understanding of aluminum-containing composite propellant combustion behavior.

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白中元,余永刚. 含超细铝粉AP/HTPB复合固体推进剂的燃烧特性研究[J]. 含能材料,DOI:10.11943/CJEM2025173.

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  • 收稿日期: 2025-08-04
  • 最后修改日期: 2025-12-02
  • 录用日期: 2025-12-16
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