CHINESE JOURNAL OF ENERGETIC MATERIALS
+Advanced Search

Synthesis and Properties of Novel Neutral Macromolecular Bonding Agents
Author:
Affiliation:

1.College of Chemistry and Chemical Engineering, Hunan University;2.College of Materials Science and Engineering, Hunan University

Fund Project:

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
    Abstract:

    To achieve uniform structural composition of neutral macromolecular bonding agents and enhance their comprehensive performance, a novel monomer, cyanoethyl acrylate (CEA), was designed and synthesized. Through free radical copolymerization with hydroxyethyl acrylate (HEA), a new type of neutral macromolecular bonding agent was prepared. The structures of monomers and polymers were characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR), and the hydroxyl value and glass transition temperature (Tg) were determined. The bonding agent was applied in NEPE high-energy propellant formulations to investigate its impact on the process and mechanical properties. Results show that CEA and HEA exhibit matched polymerization reactivity, enabling the production of structurally homogeneous copolymers without controlling the feed method. Compared to traditional neutral bonding agents, this bonding agent reduces the yield value of propellant slurry to 74.4 Pa and apparent viscosity to 337 Pa·s, making a notable improvement of processing performance. The propellant grain achieves tensile strength of 0.98 MPa and maximum elongation of 70.1% at ambient temperature, representing 22.5% and 27.5% improvements respectively.

    Reference
    Related
    Cited by
Article Metrics
  • PDF:
  • HTML:
  • Abstract:
  • Cited by:
Get Citation

蓝相涛,张平安,袁剑民,等.新型中性大分子键合剂的合成与性能[J].含能材料,2025,33(8):829-835.
LAN Xiang-tao, ZHANG Ping-an, YUAN Jian-min, et al. Synthesis and Properties of Novel Neutral Macromolecular Bonding Agents[J]. Chinese Journal of Energetic Materials,2025,33(8):829-835.

Cope
History
  • Received:June 19,2025
  • Revised:August 25,2025
  • Adopted:August 23,2025
  • Online: August 23,2025
  • Published: