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Development and Multidimensional Evaluation Framework of Aroylhydrazone-Based Gel Fuels
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Beijing Institute of Technology, School of Chemistry and Chemical Engineering

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    Abstract:

    To investigate the effect of low-molecule-weight gelators on the overall performance of gel fuels, five acylhydrazone-based low-molecular-weight gelators were designed and synthesized. Kerosene gel fuels were prepared using the heating-cooling method, and the gelation mechanism was examined. A comprehensive evaluation system for gelator performance was established based on six parameters: the minimum addition amount of gelators (A), the phase transition temperature (Tg), the physicochemical stability (Spc), the loss rate of energy density (Eloss), the shear thinning capacity (Sthin) and the resetting property (R). The results showed that all gelators could form three-dimensional network structures through non-covalent interactions such as hydrogen bonds and π-π conjugation, effectively confining kerosene molecules. Their gel fuels exhibited thermal reversibility (Tg = 50-80 ℃) and had good physical and chemical stability and shear thinning behavior. Among them, L18 gelator had the lowest minimum addition amount (3.1%) and the fastest gelation speed (15 s). L5 gelator had the best physical and chemical stability and the mass retention rate was 97.5% at a high centrifugal speed of 10000 r·min-1. L16 gelator had the strongest shear thinning ability, with a viscosity of only 34.72 mPa·s after shearing. The conclusion indicated that based on the multi-dimensional performance evaluation system established by the institute, L16 and L18 gelators demonstrated significant comprehensive advantages.

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LIU Jin-ming, ZHAO Xin, LI Wei, et al. Development and Multidimensional Evaluation Framework of Aroylhydrazone-Based Gel Fuels[J]. Chinese Journal of Energetic Materials(Hanneng Cailiao),DOI:10.11943/CJEM2026002.

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History
  • Received:December 31,2025
  • Revised:March 20,2026
  • Adopted:March 08,2026
  • Online: March 17,2026
  • Published: